X-Ray Photoelectron Spectroscopic Studies of the Charged State of 3d Metal Ions in CuCr1-X vXs2 (X = 0-0.4) Full article
Journal |
Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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Output data | Year: 2009, Volume: 50, Number: 3, Pages: 439-445 Pages count : 4 DOI: 10.1007/s10947-009-0066-3 | ||||||
Tags | Auger spectroscopy, Cation-substituted disulfides, X-ray photoelectron spectroscopy | ||||||
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Abstract:
The charged state of the 3d metal ions in layered cation-substituted disulfides CuCr1−x V x S2 was studied by X-ray photoelectron spectroscopy. An analysis of the energy positions and structure of the Cu2p 3/2 and Cr2p 3/2 X-ray photoelectron lines showed that the corresponding polycrystalline samples of CuCr1−x V x S2 contained mixed-valence chromium and copper ions. It was shown that the charged states of chromium and copper ions depended on the concentration of vanadium cations (x). The presence of mixed-valence Cu1+ and Cu2+ ions in CuCr1−x V x S2 may be correlated with the crystal structure of the corresponding layered disulfides.
Cite:
Mazalov L.N.
, Sokolov V.V.
, Kryuchkova N.A.
, Vovk E.I.
, Filatova I.Y.
, Abramova G.M.
X-Ray Photoelectron Spectroscopic Studies of the Charged State of 3d Metal Ions in CuCr1-X vXs2 (X = 0-0.4)
Journal of Structural Chemistry. 2009. V.50. N3. P.439-445. DOI: 10.1007/s10947-009-0066-3 WOS Scopus РИНЦ
X-Ray Photoelectron Spectroscopic Studies of the Charged State of 3d Metal Ions in CuCr1-X vXs2 (X = 0-0.4)
Journal of Structural Chemistry. 2009. V.50. N3. P.439-445. DOI: 10.1007/s10947-009-0066-3 WOS Scopus РИНЦ
Original:
Мазалов Л.Н.
, Соколов В.В.
, Крючкова Н.А.
, Вовк Е.И.
, Филатова И.Ю.
, Абрамова Г.М.
Рентгеноэлектронное изучение зарядового состояния ионов 3d-металлов в дисульфидах CuCr1–xVxS2 (x = 0—0,4)
Журнал структурной химии. 2009. Т.50. №3. С.461-467. RSCI РИНЦ
Рентгеноэлектронное изучение зарядового состояния ионов 3d-металлов в дисульфидах CuCr1–xVxS2 (x = 0—0,4)
Журнал структурной химии. 2009. Т.50. №3. С.461-467. RSCI РИНЦ
Dates:
Submitted: | Mar 13, 2009 |
Published print: | Jun 1, 2009 |
Published online: | Jul 17, 2009 |
Identifiers:
Web of science | WOS:000268192200008 |
Scopus | 2-s2.0-70350647646 |
Elibrary | 15303611 |
Chemical Abstracts | 2009:864347 |
Chemical Abstracts (print) | 153:607113 |
OpenAlex | W2012061848 |