EXAFS Characterisation of Metal Bonding in Highly Luminescent, UV Stable, Water-Soluble and Biocompatible Lanthanide Complexes Full article
Conference |
16th International Conference on X-ray Absorption Fine Structure 23-28 Aug 2015 , Karlsruhe |
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Journal |
Journal of Physics: Conference Series
ISSN: 1742-6588 , E-ISSN: 1742-6596 |
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Output data | Year: 2016, Volume: 712, Article number : 012137, Pages count : 5 DOI: 10.1088/1742-6596/712/1/012137 | ||||||||||
Tags | Atomic physics; Biocompatibility; Coordination reactions; Methanol; Rare earth elements; X ray absorption; X ray diffraction | ||||||||||
Authors |
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Abstract:
The combination of X-ray diffraction with EXAFS was employed to assess the coordination environment of lanthanide complexes in solutions. This method is based on the assumption that the local structure of lanthanide complexes in solution combines elements of the crystal structure of the complex in the solid state (single- or polycrystalline) and the elements of the local structure of a lanthanide salt, completely dissociated in the solvent (usually chlorides). The success of this approach is demonstrated with the lanthanide (III) 2,3,4,5,6-pentafluorobenzoate complexes, where the local structure in aqueous and methanol solutions were estimated. Moreover, the dissociation degree of the complexes in aqueous and methanol solutions was evaluated.
Cite:
Kalyakina A.
, Utochnikova V.
, Trigub A.
, Zubavichus Y.
, Kuzmina N.
, Bräse S.
EXAFS Characterisation of Metal Bonding in Highly Luminescent, UV Stable, Water-Soluble and Biocompatible Lanthanide Complexes
Journal of Physics: Conference Series. 2016. V.712. 012137 :1-5. DOI: 10.1088/1742-6596/712/1/012137 WOS Scopus РИНЦ
EXAFS Characterisation of Metal Bonding in Highly Luminescent, UV Stable, Water-Soluble and Biocompatible Lanthanide Complexes
Journal of Physics: Conference Series. 2016. V.712. 012137 :1-5. DOI: 10.1088/1742-6596/712/1/012137 WOS Scopus РИНЦ
Files:
Full text from publisher
Dates:
Submitted: | Apr 15, 2016 |
Published print: | May 1, 2016 |
Published online: | Jun 2, 2016 |
Identifiers:
Web of science | WOS:000383249000138 |
Scopus | 2-s2.0-84978715230 |
Elibrary | 27075459 |
Chemical Abstracts | 2017:633821 |
Chemical Abstracts (print) | 167:535389 |
OpenAlex | W2415499096 |