Kinetic Aspects of Stereoselectivity in Hydrogenation of Fatty Acids Full article
Journal |
Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169 |
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Output data | Year: 2008, Volume: 286, Number: 1-2, Pages: 156-161 Pages count : 6 DOI: 10.1016/j.molcata.2008.02.020 | ||||
Tags | Fatty acids, Hydrogenation, Kinetics, Stereoselectivity | ||||
Authors |
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Affiliations |
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Funding (1)
1 | Suomen Akatemia |
Abstract:
Kinetic peculiarities of stereoselectivity in hydrogenation of fatty acids are discussed. The reaction mechanism should be able to account for independence of the reaction rate on hydrogen pressure and conversion, stereoselectivity on conversion as well as an increase in cis/trans ratio with pressure increase. Various mechanisms advanced in the literature for formation of cis- and trans mono-unsaturated acids and their derivatives are considered, showing behavior contradicting with experiments. A reaction mechanism is proposed, which is consistent with experimental observations.
Cite:
Murzin D.Y.
, Simakova I.L.
Kinetic Aspects of Stereoselectivity in Hydrogenation of Fatty Acids
Journal of Molecular Catalysis A: Chemical. 2008. V.286. N1-2. P.156-161. DOI: 10.1016/j.molcata.2008.02.020 WOS Scopus РИНЦ
Kinetic Aspects of Stereoselectivity in Hydrogenation of Fatty Acids
Journal of Molecular Catalysis A: Chemical. 2008. V.286. N1-2. P.156-161. DOI: 10.1016/j.molcata.2008.02.020 WOS Scopus РИНЦ
Dates:
Submitted: | Jan 20, 2008 |
Accepted: | Feb 19, 2008 |
Published online: | Feb 29, 2008 |
Published print: | May 1, 2008 |
Identifiers:
Web of science | WOS:000256724800024 |
Scopus | 2-s2.0-43049175133 |
Elibrary | 13587103 |
Chemical Abstracts | 2008:581515 |
Chemical Abstracts (print) | 149:332072 |
OpenAlex | W2038277858 |