Pulsed EPR Study of the (NO)2–Na+ Triplet State Adsorption Complex Full article
Journal |
Chemical Physics Letters
ISSN: 0009-2614 , E-ISSN: 1873-4448 |
||||
---|---|---|---|---|---|
Output data | Year: 2001, Volume: 349, Number: 5-6, Pages: 511-516 Pages count : 6 DOI: 10.1016/S0009-2614(01)01250-7 | ||||
Tags | ECHO ENVELOPE MODULATION; NITRIC-OXIDE ADSORPTION; QUADRUPOLE INTERACTIONS; ELECTRONIC STATES; SPIN; ZEOLITES; SPECTROSCOPY; RESONANCE; DIMER; BAND | ||||
Authors |
|
||||
Affiliations |
|
Funding (3)
1 | Russian Foundation for Basic Research | 00-03-32441 |
2 | Swedish Research Council | |
3 | Royal Swedish Academy of Sciences |
Abstract:
The (NO)2–Na+ triplet state complex stabilised in Na–A zeolites at low temperature was studied by pulsed EPR. The 3-pulse ESEEM spectra at 5 K were analysed by simulations in the time-domain, followed by Fourier transformation. The ESEEM was attributed to the interaction with Na+. The hyperfine coupling A(23Na) = (4.6, 4.6, 8.2) MHz and nuclear quadrupole Q(23Na) = (0.3, 0,3, −0.6) MHz tensors are of comparable magnitude as in the NO–Na+ complex determined earlier. The complexes are proposed to be either pairs of NO–Na+ or ON–Na+–NO.
Cite:
Biglino D.
, Bonora M.
, Volodin A.
, Lund A.
Pulsed EPR Study of the (NO)2–Na+ Triplet State Adsorption Complex
Chemical Physics Letters. 2001. V.349. N5-6. P.511-516. DOI: 10.1016/S0009-2614(01)01250-7 WOS Scopus РИНЦ
Pulsed EPR Study of the (NO)2–Na+ Triplet State Adsorption Complex
Chemical Physics Letters. 2001. V.349. N5-6. P.511-516. DOI: 10.1016/S0009-2614(01)01250-7 WOS Scopus РИНЦ
Dates:
Submitted: | Jul 11, 2001 |
Accepted: | Oct 15, 2001 |
Published online: | Nov 20, 2001 |
Published print: | Dec 7, 2001 |
Identifiers:
Web of science | WOS:000172756100027 |
Scopus | 2-s2.0-0010352488 |
Elibrary | 13383414 |
Chemical Abstracts | 2002:1984 |
Chemical Abstracts (print) | 136:237331 |
OpenAlex | W2013155294 |