Synthesis and Structural Features of Nanostructured Cuprous Chloride with High Catalytic Activity
Science article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Original
|
| Journal |
Silicon
ISSN: 1876-990X
, E-ISSN: 1876-9918
|
| Output data |
Year: 2015,
Volume: 7,
Number: 2,
Pages: 79-87
Pages count
: 8
DOI:
10.1007/s12633-014-9272-5
|
| Tags |
Copper catalyst, Cuprous chloride, Direct synthesis, Nanoparticles, Nanostructured, Silicon, Trialkoxysilanes, Triethoxysilane |
| Authors |
Adonin Nicolay Yu.
1
,
Prikhodʹko Sergey A.
1
,
Shabalin Anton Yu.
1
,
Prosvirin Igor P.
1
,
Zaikovskii Vladimir I.
1,2
,
Kochubey Dmitry I.
1
,
Zyuzin Dmitry A.
1
,
Parmon Valentin N.
1
,
Monin Evgeny A.
3
,
Bykova Irina A.
3
,
Martynov Petr O.
3
,
Rusakov Sergey L.
3
,
Storozhenko Pavel A.
3
|
| Affiliations |
| 1 |
G.K. Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia
|
| 2 |
Novosibirsk State University, Novosibirsk, Russia
|
| 3 |
The State Scientific Center of the Russian Federation State
Research Institute for Chemistry and Technology
of Organoelement Compounds, Moscow, Russia
|
|
Funding (1)
|
1
|
Russian Foundation for Basic Research
|
13-03-12246
|
A method for nanostructured cuprous chloride preparation by reductive thermolysis of a CuCl2⋅2H2O and Cu(OH)2 mixture in glycerol has been developed. The resultant CuCl was characterized with infrared spectroscopy, X-ray photoelectron spectroscopy, EXAFS spectroscopy, X-ray diffraction, scanning electron microscopy, and transmission electron microscopy. The prepared samples of CuCl demonstrated high catalytic activity in the “direct synthesis” of triethoxysilane.