Attrition-Induced Spontaneous Chiral Amplification of the γ Polymorphic Modification of Glycine Full article
Journal |
CrystEngComm
ISSN: 1466-8033 |
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Output data | Year: 2015, Volume: 17, Pages: 1513-1517 Pages count : 5 DOI: 10.1039/C4CE02434F | ||||||||
Tags | SYMMETRY BREAKING CRYSTALLIZATION; SODIUM-CHLORATE; AMINO-ACID; STIRRED CRYSTALLIZATION; SPONTANEOUS GENERATION; CRYSTAL-STRUCTURE; OPTICAL-ACTIVITY; HIGH-PRESSURE; DERACEMIZATION; 1,1-BINAPHTHYL | ||||||||
Authors |
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Affiliations |
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Funding (4)
1 | French National Centre for Scientific Research | |
2 | National Centre for Space Studies | |
3 | The French National Research Agency | ANR-10-BLAN-724-1-NCPCHEM |
4 | Ministry of Education and Science | M/164-2014 |
Abstract:
Glycine is the simplest achiral amino acid that undergoes spontaneous mirror symmetry breaking when it crystallizes in its chiral γ-polymorphic modification. As a result of Ostwald ripening, its racemic mixture stochastically becomes optically active. The sense of the resulting handedness can be controlled by addition of one enantiomer of a simple chiral amino acid, the alanine.
Cite:
Tarasevych A.V.
, Sorochinsky A.E.
, Kukhar V.P.
, Toupet L.
, Crassous J.
, Guillemin J-C.
Attrition-Induced Spontaneous Chiral Amplification of the γ Polymorphic Modification of Glycine
CrystEngComm. 2015. V.17. P.1513-1517. DOI: 10.1039/C4CE02434F WOS Scopus РИНЦ
Attrition-Induced Spontaneous Chiral Amplification of the γ Polymorphic Modification of Glycine
CrystEngComm. 2015. V.17. P.1513-1517. DOI: 10.1039/C4CE02434F WOS Scopus РИНЦ
Files:
Full text from publisher
Dates:
Submitted: | Dec 9, 2014 |
Accepted: | Jan 6, 2015 |
Published online: | Jan 15, 2015 |
Identifiers:
Web of science | WOS:000349309700002 |
Scopus | 2-s2.0-84922513747 |
Elibrary | 23972222 |
Chemical Abstracts | 2015:86165 |
Chemical Abstracts (print) | 162:341087 |
OpenAlex | W2146132781 |