Evidence for the Formation of an Iodosylbenzene(salen)iron Active Intermediate in a (Salen)iron(iii)-Catalyzed Asymmetric Sulfide Oxidation Full article
Journal |
Angewandte Chemie - International Edition
ISSN: 1433-7851 , E-ISSN: 1521-3773 |
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Output data | Year: 2004, Volume: 43, Number: 39, Pages: 5228-5230 Pages count : 3 DOI: 10.1002/anie.200460108 | ||
Tags | Asymmetric catalysis, Enantioselectivity, Iron, Oxidation, Sulfides | ||
Authors |
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Affiliations |
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Funding (1)
1 | Russian Foundation for Basic Research | 03-03-32009 |
Abstract:
Catalytic converter: A (salen)iron(iii) complex (salen*=asymmetric bis(salicylidene)ethylenediamine ligand) can be used as a catalyst system for the asymmetric oxidation of aryl sulfides by iodosylbenzene (see scheme). An iodosylbenzene(salen)iron(iii) species has been identified as the active intermediate by EPR and NMR spectroscopy. R=aryl, R′=alkyl.
Cite:
Bryliakov K.P.
, Talsi E.P.
Evidence for the Formation of an Iodosylbenzene(salen)iron Active Intermediate in a (Salen)iron(iii)-Catalyzed Asymmetric Sulfide Oxidation
Angewandte Chemie - International Edition. 2004. V.43. N39. P.5228-5230. DOI: 10.1002/anie.200460108 WOS Scopus РИНЦ
Evidence for the Formation of an Iodosylbenzene(salen)iron Active Intermediate in a (Salen)iron(iii)-Catalyzed Asymmetric Sulfide Oxidation
Angewandte Chemie - International Edition. 2004. V.43. N39. P.5228-5230. DOI: 10.1002/anie.200460108 WOS Scopus РИНЦ
Original:
Bryliakov K.P.
, Talsi E.P.
Evidence for the Formation of an Iodosylbenzene(salen)iron Active Intermediate in a (Salen)iron(III)-Catalyzed Asymmetric Sulfide Oxidation
Angewandte Chemie (German edition). 2004. Т.116. №39. С.5340-5342. DOI: 10.1002/ange.200460108 РИНЦ
Evidence for the Formation of an Iodosylbenzene(salen)iron Active Intermediate in a (Salen)iron(III)-Catalyzed Asymmetric Sulfide Oxidation
Angewandte Chemie (German edition). 2004. Т.116. №39. С.5340-5342. DOI: 10.1002/ange.200460108 РИНЦ
Dates:
Submitted: | Mar 24, 2004 |
Published online: | Sep 29, 2004 |
Published print: | Oct 4, 2004 |
Identifiers:
Web of science | WOS:000224424600022 |
Scopus | 2-s2.0-6044234865 |
Elibrary | 13467846 |
Chemical Abstracts | 2004:868318 |
Chemical Abstracts (print) | 142:55950 |
PMID | 15455434 |
OpenAlex | W2109805812 |