Optically Active Complexes (μ-H)Os3(μ-OCNH-(R)-CHMePh)(CO)10: The Absolute Configuration of the (+)-Rotating Stereoisomer Full article
Journal |
Inorganic Chemistry Communications
ISSN: 1387-7003 |
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Output data | Year: 2002, Volume: 5, Number: 11, Pages: 963-965 Pages count : 3 DOI: 10.1016/S1387-7003(02)00613-5 | ||
Tags | Absolute configuration, Triosinium chiral clusters, X-ray analysis | ||
Authors |
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Affiliations |
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Funding (1)
1 | Russian Foundation for Basic Research | 01-03-32426 |
Abstract:
Room-temperature interaction between Os3(CO)11NCMe and (R)-(+)-1-phenylethylamine at ambient temperature in THF gives two known diastereomeric clusters (μ-H)Os3(μ-OCNH-(R)-CHMePh)(CO)10 in an approximate ratio 1:2. 1H-NMR, IR and [α]D characteristics are described for them. The (+)-diastereomer characterized by absolute-configugational data obtained from the X-ray analysis of its single crystal.
Cite:
Ershova V.A.
, Virovets A.V.
, Pogrebnyak V.M.
, Golovin A.V.
Optically Active Complexes (μ-H)Os3(μ-OCNH-(R)-CHMePh)(CO)10: The Absolute Configuration of the (+)-Rotating Stereoisomer
Inorganic Chemistry Communications. 2002. V.5. N11. P.963-965. DOI: 10.1016/S1387-7003(02)00613-5 WOS Scopus РИНЦ
Optically Active Complexes (μ-H)Os3(μ-OCNH-(R)-CHMePh)(CO)10: The Absolute Configuration of the (+)-Rotating Stereoisomer
Inorganic Chemistry Communications. 2002. V.5. N11. P.963-965. DOI: 10.1016/S1387-7003(02)00613-5 WOS Scopus РИНЦ
Dates:
Submitted: | Aug 6, 2002 |
Accepted: | Aug 23, 2002 |
Published print: | Oct 1, 2002 |
Published online: | Oct 10, 2002 |
Identifiers:
Web of science | WOS:000178953000012 |
Scopus | 2-s2.0-0036829219 |
Elibrary | 13392686 |
Chemical Abstracts | 2002:801560 |
Chemical Abstracts (print) | 138:153650 |
OpenAlex | W2002597623 |