The IRS-DR Study of Interaction of the Supported Catalyst Based on the Organic Nickel Chelate with Carbon Monoxide and Ethylene Full article
Journal |
Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169 |
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Output data | Year: 1998, Volume: 135, Number: 2, Pages: 115-120 Pages count : 6 DOI: 10.1016/S1381-1169(97)00300-2 | ||
Tags | Carbon monoxide, IRS-DS, Organic nickel chelate compound, Supported nickel catalysts | ||
Authors |
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Abstract:
The interaction of the supported catalyst based on the organic nickel chelate compound (I) with carbon monoxide and deuterated ethylene has been studied using IRS–DS. The surface nickel compound (SNC) interacts with carbon monoxide in the same manner as the initial nickel complex (I). The reaction of SNC or nickel complex (I) with CO yields nickel acyl complex (V) (a product of the CO insertion into the Ni–Ph bond), ester (VIII) and various nickel carbonyls (VI). According to the IRS data, the interaction between SNC and deuterated ethylene gives a polymer. The subsequent carbon monoxide introduction results in the same products as in the case of the CO reaction with SNC. The interaction between ethylene and SNC pretreated with carbon monoxide does not lead to polymerization.
Cite:
Panchenko V.N.
, Zakharov V.A.
, Paukshtis E.A.
The IRS-DR Study of Interaction of the Supported Catalyst Based on the Organic Nickel Chelate with Carbon Monoxide and Ethylene
Journal of Molecular Catalysis A: Chemical. 1998. V.135. N2. P.115-120. DOI: 10.1016/S1381-1169(97)00300-2 WOS Scopus РИНЦ
The IRS-DR Study of Interaction of the Supported Catalyst Based on the Organic Nickel Chelate with Carbon Monoxide and Ethylene
Journal of Molecular Catalysis A: Chemical. 1998. V.135. N2. P.115-120. DOI: 10.1016/S1381-1169(97)00300-2 WOS Scopus РИНЦ
Dates:
Submitted: | Mar 15, 1997 |
Accepted: | Nov 21, 1997 |
Published online: | Oct 13, 1998 |
Published print: | Oct 14, 1998 |
Identifiers:
Web of science | WOS:000076564300001 |
Scopus | 2-s2.0-0032517328 |
Elibrary | 13297357 |
Chemical Abstracts | 1998:626692 |
Chemical Abstracts (print) | 130:66829 |
OpenAlex | W2000223385 |