Co Adsorption on Au(110)-(1 × 2): An IRAS Investigation Full article
Journal |
The Journal of Physical Chemistry B
ISSN: 1520-6106 , E-ISSN: 1520-5207 |
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Output data | Year: 2003, Volume: 107, Number: 46, Pages: 12668-12671 Pages count : 4 DOI: 10.1021/jp030499u | ||||
Tags | Absorption spectroscopy; Adsorption; Bonding; Carbon monoxide; Catalysts; Chemical bonds; Coordination reactions; Data reduction; Enthalpy; Single crystals; Surface phenomena; Ultrahigh vacuum | ||||
Authors |
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Affiliations |
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Funding (3)
1 | United States Department of Energy | |
2 | Welch Foundation | |
3 | Texas A&M University | 010366-0022-2001 |
Abstract:
IRAS studies of CO adsorption on the Au(110)−(1 × 2) surface were performed as a function of CO pressure and sample temperature. It was found that with increasing coverage, the CO IRAS absorption shifts red from 2118 to 2108 cm-1. Clausius−Clapeyron data analysis yielded a heat of CO adsorption (−ΔHads) of 10.9 kcal/mol at low coverages and 7.8 kcal/mol at coverages greater than 19%.
Cite:
Meier D.C.
, Bukhtiyarov V.
, Goodman D.W.
Co Adsorption on Au(110)-(1 × 2): An IRAS Investigation
The Journal of Physical Chemistry B. 2003. V.107. N46. P.12668-12671. DOI: 10.1021/jp030499u WOS Scopus РИНЦ
Co Adsorption on Au(110)-(1 × 2): An IRAS Investigation
The Journal of Physical Chemistry B. 2003. V.107. N46. P.12668-12671. DOI: 10.1021/jp030499u WOS Scopus РИНЦ
Dates:
Submitted: | Apr 24, 2003 |
Published print: | Nov 1, 2003 |
Identifiers:
Web of science | WOS:000186574500021 |
Scopus | 2-s2.0-0344718926 |
Elibrary | 13421869 |
Chemical Abstracts | 2003:837741 |
Chemical Abstracts (print) | 140:48152 |
OpenAlex | W2149890763 |