Surface Restructuring, Kinetic Oscillations, and Chaos in Heterogeneous Catalytic Reactions Full article
| Conference |
NATO workshop "Nonlinear Science: Dynamics and Stochasticity' 30 Jun - 3 Jul 1999 , Brussels |
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| Journal |
Journal of Statistical Physics
ISSN: 0022-4715 , E-ISSN: 1572-9613 |
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| Output data | Year: 2000, Volume: 101, Number: 1-2, Pages: 631-647 Pages count : 17 DOI: 10.1023/A:1026470307071 | ||||
| Tags | Computer simulations, Models of surface chemical reactions, Surface reconstruction | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | University of Gothenburg |
Abstract:
Kinetic oscillations in catalytic reactions on single-crystal surfaces often result from the interplay of the purely chemical reaction steps and adsorbate-induced surface restructuring. A classical example is CO oxidation on Pt(100). We survey evolution of the models used to simulate this reaction and show how it can be described self-consistently by employing Monte Carlo simulations combined with the lattice-gas model, taking into account substrate-substrate, substrate-adsorbate and adsorbate-adsorbate lateral interactions. Under the reactive conditions, this approach predicts formation of mesoscopic restructured well ordered islands with atomically sharp boundaries.
Cite:
Zhdanov V.P.
, Kasemo B.
Surface Restructuring, Kinetic Oscillations, and Chaos in Heterogeneous Catalytic Reactions
Journal of Statistical Physics. 2000. V.101. N1-2. P.631-647. DOI: 10.1023/A:1026470307071 WOS Scopus РИНЦ OpenAlex
Surface Restructuring, Kinetic Oscillations, and Chaos in Heterogeneous Catalytic Reactions
Journal of Statistical Physics. 2000. V.101. N1-2. P.631-647. DOI: 10.1023/A:1026470307071 WOS Scopus РИНЦ OpenAlex
Dates:
| Submitted: | Jun 30, 1999 |
| Accepted: | Feb 15, 2000 |
| Published print: | Oct 1, 2000 |
Identifiers:
| ≡ Web of science: | WOS:000165958100039 |
| ≡ Scopus: | 2-s2.0-0034287929 |
| ≡ Elibrary: | 13340171 |
| ≡ OpenAlex: | W2999228659 |