Role of Phosphates in the Promotion of Silver Catalysts for Partial Oxidation: I. Structure and Properties of Phosphates on the Surface of Polycrystalline Silver Full article
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2005, Volume: 46, Number: 1, Pages: 144-150 Pages count : 7 DOI: 10.1007/s10975-005-0022-y | ||||||
| Tags | Oxidation; Oxygen; Phosphate; Physical Chemistry; Heat Treatment | ||||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | The Ministry of Education and Science of the Russian Federation | E02-5.0-340 |
| 2 | Council for Grants of the President of the Russian Federation | МД-243.2003.03 |
Abstract:
The chemical composition, structure, and properties of an H3PO4-promoted polycrystalline silver foil are studied by XPS. The surface of the doped sample contains oxygen in two states with binding energies of 531.1 and 533.0 eV. Heat treatment results in silver clusters distributed in the polyphosphate matrix. It follows from TDS data that the surface of the promoted catalyst contains a strongly bound oxygen species that desorbs at ~900 K. It is believed that the silver clusters stabilized by the phosphate matrix are active sites on the surface of the phosphorus-promoted catalyst.
Cite:
Knyazev A.S.
, Boronin A.I.
, Vodyankina O.V.
, Koshcheev S.V.
, Kurina L.N.
Role of Phosphates in the Promotion of Silver Catalysts for Partial Oxidation: I. Structure and Properties of Phosphates on the Surface of Polycrystalline Silver
Kinetics and Catalysis. 2005. V.46. N1. P.144-150. DOI: 10.1007/s10975-005-0022-y WOS Scopus РИНЦ ANCAN OpenAlex
Role of Phosphates in the Promotion of Silver Catalysts for Partial Oxidation: I. Structure and Properties of Phosphates on the Surface of Polycrystalline Silver
Kinetics and Catalysis. 2005. V.46. N1. P.144-150. DOI: 10.1007/s10975-005-0022-y WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Князев А.С.
, Боронин А.И.
, Водянкина О.В.
, Кощеев С.В.
, Курина Л.Н.
Роль фосфатов в промотировании серебряных катализаторов парциального окисления. I. Структура и свойства фосфатов на поверхности поликристаллического серебра
Кинетика и катализ. 2005. Т.46. №1. С.153-160. RSCI РИНЦ
Роль фосфатов в промотировании серебряных катализаторов парциального окисления. I. Структура и свойства фосфатов на поверхности поликристаллического серебра
Кинетика и катализ. 2005. Т.46. №1. С.153-160. RSCI РИНЦ
Dates:
| Submitted: | Sep 29, 2003 |
| Published print: | Jan 1, 2005 |
Identifiers:
| Web of science: | WOS:000227731700022 |
| Scopus: | 2-s2.0-15444377505 |
| Elibrary: | 13497087 |
| Chemical Abstracts: | 2005:197944 |
| Chemical Abstracts (print): | 142:380077 |
| OpenAlex: | W1997564427 |