Propane Oxidation on Nickel in a Self-Oscillation Mode Full article
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2005, Volume: 46, Number: 2, Pages: 251-259 Pages count : 9 DOI: 10.1007/s10975-005-0071-2 | ||
| Tags | Oxidation; Oxygen; Spectroscopy; Physical Chemistry; Nickel | ||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Russian Foundation for Basic Research | 04-03-32667 |
| 2 | Council for Grants of the President of the Russian Federation | НШ-1484.2003.3 |
Abstract:
The kinetics of the catalytic oxidation of propane with oxygen on nickel in a self-oscillation mode was studied. A comparative analysis of changes in reaction rate oscillations with time in the presence of nickel wire and foil was performed. It was found that the reaction medium influenced the morphology of the catalyst surface. With the use of X-ray photoelectron spectroscopy, it was demonstrated that a NiO layer no less than 100 nm in thickness was formed on the catalyst surface in the course of the reaction of propane oxidation. The mechanism of the appearance of self-oscillations in the test system is discussed.
Cite:
Gladky A.Y.
, Kaichev V.V.
, Ermolaev V.K.
, Bukhtiyarov V.I.
, Parmon V.N.
Propane Oxidation on Nickel in a Self-Oscillation Mode
Kinetics and Catalysis. 2005. V.46. N2. P.251-259. DOI: 10.1007/s10975-005-0071-2 WOS Scopus РИНЦ OpenAlex ANCAN
Propane Oxidation on Nickel in a Self-Oscillation Mode
Kinetics and Catalysis. 2005. V.46. N2. P.251-259. DOI: 10.1007/s10975-005-0071-2 WOS Scopus РИНЦ OpenAlex ANCAN
Original:
Гладкий А.Ю.
, Каичев В.В.
, Ермолаев В.К.
, Бухтияров В.И.
, Пармон В.Н.
Окисление пропана на никеле в режиме автоколебаний
Кинетика и катализ. 2005. Т.46. №2. С.269-277. РИНЦ RSCI
Окисление пропана на никеле в режиме автоколебаний
Кинетика и катализ. 2005. Т.46. №2. С.269-277. РИНЦ RSCI
Dates:
| Submitted: | Jul 16, 2003 |
| Published print: | Mar 1, 2005 |
Identifiers:
| ≡ Web of science: | WOS:000228933000007 |
| ≡ Scopus: | 2-s2.0-18244385736 |
| ≡ Elibrary: | 13491909 |
| ≡ OpenAlex: | W1974729300 |
| ≡ Chemical Abstracts: | 2005:380939 |
| ≡ Chemical Abstracts (print): | 143:29086 |