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Propane Oxidation on Nickel in a Self-Oscillation Mode Full article

Journal Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Output data Year: 2005, Volume: 46, Number: 2, Pages: 251-259 Pages count : 9 DOI: 10.1007/s10975-005-0071-2
Tags Oxidation; Oxygen; Spectroscopy; Physical Chemistry; Nickel
Authors Gladky A.Y. 1 , Kaichev V.V. 1 , Ermolaev V.K. 1 , Bukhtiyarov V.I. 1 , Parmon V.N. 1
Affiliations
1 Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences

Funding (2)

1 Russian Foundation for Basic Research 04-03-32667
2 Council for Grants of the President of the Russian Federation НШ-1484.2003.3

Abstract: The kinetics of the catalytic oxidation of propane with oxygen on nickel in a self-oscillation mode was studied. A comparative analysis of changes in reaction rate oscillations with time in the presence of nickel wire and foil was performed. It was found that the reaction medium influenced the morphology of the catalyst surface. With the use of X-ray photoelectron spectroscopy, it was demonstrated that a NiO layer no less than 100 nm in thickness was formed on the catalyst surface in the course of the reaction of propane oxidation. The mechanism of the appearance of self-oscillations in the test system is discussed.
Cite: Gladky A.Y. , Kaichev V.V. , Ermolaev V.K. , Bukhtiyarov V.I. , Parmon V.N.
Propane Oxidation on Nickel in a Self-Oscillation Mode
Kinetics and Catalysis. 2005. V.46. N2. P.251-259. DOI: 10.1007/s10975-005-0071-2 WOS Scopus РИНЦ ANCAN OpenAlex
Original: Гладкий А.Ю. , Каичев В.В. , Ермолаев В.К. , Бухтияров В.И. , Пармон В.Н.
Окисление пропана на никеле в режиме автоколебаний
Кинетика и катализ. 2005. Т.46. №2. С.269-277. RSCI РИНЦ
Dates:
Submitted: Jul 16, 2003
Published print: Mar 1, 2005
Identifiers:
Web of science: WOS:000228933000007
Scopus: 2-s2.0-18244385736
Elibrary: 13491909
Chemical Abstracts: 2005:380939
Chemical Abstracts (print): 143:29086
OpenAlex: W1974729300
Citing:
DB Citing
Web of science 22
Scopus 21
Elibrary 20
OpenAlex 21
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