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TiO2 Photocatalytic Oxidation: II. Gas-Phase Processes Full article

Journal Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Output data Year: 2005, Volume: 46, Number: 3, Pages: 422–436 Pages count : 15 DOI: 10.1007/s10975-005-0095-7
Tags TiO2; Sulfide; Reaction Center; Organic Substance; Photocatalytic Degradation
Authors Vorontsov A.V. 1 , Kozlov D.V. 1 , Smirniotis P.G. 2 , Parmon V.N. 1
Affiliations
1 Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences
2 University of Cincinnati

Funding (5)

1 Russian Foundation for Basic Research 02-03-08002
2 Academy of Finland 208134
3 Civilian Research and Development Foundation NO-008-X1
4 Russian Science Support Foundation
5 Council for Grants of the President of the Russian Federation НШ-1484.2003.3

Abstract: The results of studies on the TiO2 photocatalytic oxidation of model air pollutants are summarized. The kinetics of photocatalytic oxidation of CO and the vapors of a number of simple organic substances was studied in detail. It was found that, in the course of reaction, all of the test substances underwent complete mineralization. Gaseous substrates were converted with the participation of several types of reaction centers. The photocatalytic oxidation of sulfur- and phosphorus-containing substances resulted in gradual deactivation of the photocatalyst; however, its activity can be restored by washing the photocatalyst with water. It was found that, along with oxidation, the steps of hydrolysis play an important role in the photocatalytic degradation of air pollutants, such as dimethyl methylphosphonate and 2-chloroethyl sulfide.
Cite: Vorontsov A.V. , Kozlov D.V. , Smirniotis P.G. , Parmon V.N.
TiO2 Photocatalytic Oxidation: II. Gas-Phase Processes
Kinetics and Catalysis. 2005. V.46. N3. P.422–436. DOI: 10.1007/s10975-005-0095-7 WOS Scopus РИНЦ РИНЦ ANCAN OpenAlex
Original: Воронцов А.В. , Козлов Д.В. , Смирниотис П.Г. , Пармон В.Н.
Фотокаталитическое окисление на ТiO2 II. Процессы в газовой фазе
Кинетика и катализ. 2005. Т.46. №3. С.450-465. RSCI РИНЦ
Dates:
Submitted: Apr 30, 2004
Published print: May 1, 2005
Identifiers:
Web of science: WOS:000230024100020
Scopus: 2-s2.0-21544465063
Elibrary: 29494908 | 31122811
Chemical Abstracts: 2005:557863
Chemical Abstracts (print): 143:391443
OpenAlex: W1984430510
Citing:
DB Citing
Web of science 11
Scopus 8
Elibrary 18 1
OpenAlex 12
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