Alumina-supported Sulfided Catalysts. VI. Tetrahydrothiophene Hydrogenolysis | Sciact - CRIS-system of Boreskov Institute of Catalysis

Alumina-supported Sulfided Catalysts. VI. Tetrahydrothiophene Hydrogenolysis Full article

Journal

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Output data

Year: 1997, Volume: 38, Number: 6, Pages: 832-835 Pages count : 4

Authors

Aksenov D.G. ¹ , Klimov O.V. ¹ , Startsev A.N. ¹

Affiliations

1	Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk, 630090 Russia

The main regularities of the hydrogenolysis of tetrahydrothiophene (THT), the possible intermediate in thiophene hydrogenolysis, are examined. All kinetic regularities of the hydrogenolysis of thiophene and THT over the same catalysts are shown to be identical except for the numerical values of the parameters of these processes: the rate and the activation energy are lower in THT hydrogenolysis. A conclusion is drawn that the C-S bond hydrogenolysis is the rate-determining step in both reactions.

Aksenov D.G. , Klimov O.V. , Startsev A.N.
Alumina-supported Sulfided Catalysts. VI. Tetrahydrothiophene Hydrogenolysis
Kinetics and Catalysis. 1997. V.38. N6. P.832-835. WOS Scopus РИНЦ ANCAN

Аксенов Д.Г. , Климов О.В. , Старцев А.Н.
Нанесенные на Al2O3 сульфидные катализаторы. VI. Гидрогенолиз тетрагидротиофена
Кинетика и катализ. 1997. Т.38. №6. С.903-907. РИНЦ

Submitted:

Aug 15, 1996

Web of science:	WOS:000071180900018
Scopus:	2-s2.0-0642334716
Elibrary:	13256537
Chemical Abstracts:	1998:18782
Chemical Abstracts (print):	128:142887

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Web of science	1
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