Sulfide Catalysts for Hydrogenation of Aromatic Hydrocarbons: I. Benzene Hydrogenation and Thiophene Hydrogenolysis | Sciact - CRIS-system of Boreskov Institute of Catalysis

Sulfide Catalysts for Hydrogenation of Aromatic Hydrocarbons: I. Benzene Hydrogenation and Thiophene Hydrogenolysis Full article

Journal

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Output data

Year: 1998, Volume: 39, Number: 2, Pages: 221-228 Pages count : 8

Tags

MOLYBDENA-ALUMINA; KINETICS; HDS

Authors

Startsev A.N. ¹ , Rodin V.N. ¹ , Aleshina G.I. ¹ , Aksenov D.G. ¹

Affiliations

1	Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk, 630090 Russia

Basic characteristics of benzene hydrogenation in the presence of thiophene and of thiophene hydrogenolysis in the presence of benzene were studied. A strong inhibiting effect of benzene on thiophene hydrogenolysis was found. The data obtained for sulfide catalysts prepared by different procedures and supported on different materials suggest that both reactions proceed on the same active sites via competitive sorption of reacting molecules. Active sites responsible for benzene hydrogenation are formed from active sites for thiophene hydrogenolysis as a result of hydrogen sulfide removal.

Startsev A.N. , Rodin V.N. , Aleshina G.I. , Aksenov D.G.
Sulfide Catalysts for Hydrogenation of Aromatic Hydrocarbons: I. Benzene Hydrogenation and Thiophene Hydrogenolysis
Kinetics and Catalysis. 1998. V.39. N2. P.221-228. WOS Scopus РИНЦ ANCAN

Старцев А.Н. , Родин В.Н. , Алешина Г.И. , Аксенов Д.Г.
Сульфидные катализаторы гидрирования ароматических углеводородов. I. Гидрирование бензола и гидрогенолиз тиофена
Кинетика и катализ. 1998. Т.39. №2. С.238-245. РИНЦ

Submitted:

Dec 22, 1996

Web of science:	WOS:000073168400014
Scopus:	2-s2.0-0012314133
Elibrary:	13281549
Chemical Abstracts:	1998:265545
Chemical Abstracts (print):	129:4367

DB	Citing
Web of science	12
Scopus	4
Elibrary	4