Abstract: New metal-filamentous carbon catalytic systems, which differ fundamentally from all known catalysts in structure and preparation procedure, are found. Metal-carbon catalysts are formed by decomposition of hydrocarbons over the iron-subgroup metals or their alloys. They contain metal particles anchored at the ends of the carbon filaments. By varying the conditions of hydrocarbon decomposition, one can impart desired properties to metal-carbon systems. These properties allow the use of the catalysts in complete and selective hydrogenation of unsaturated hydrocarbons and carboxylic acids, steam and CO2 methane conversion, CO methanation, Fischer-Tropsch synthesis, hydrodechlorination of chlorobenzene, dehydrogenation of n-butane, and CO oxidation. Depending on the carbon : metal ratio, the catalysts can be active in both complete and selective hydrogenation of dienes and alkynes. At high carbon : metal ratios, the selectivity to olefins is close to 100%.

Cite: Molchanov V.V. , Chesnokov V.V. , Buyanov R.A. , Zaitseva N.A.
New Metal-Carbon Catalysts: I. Preparation Procedure and Application Area
Kinetics and Catalysis. 1998. V.39. N3. P.378-385. WOS Scopus РИНЦ ANCAN

Original: Молчанов В.В. , Чесноков В.В. , Буянов Р.А. , Зайцева Н.А.
Новые металл-углеродные катализаторы. I. Способ приготовления, область применения
Кинетика и катализ. 1998. Т.39. №3. С.407-415. РИНЦ

Dates:

Submitted:

Oct 30, 1995

Identifiers:

Web of science:	WOS:000076097900013
Scopus:	2-s2.0-0041391315
Elibrary:	13305234
Chemical Abstracts:	1998:653495
Chemical Abstracts (print):	129:236140

Citing:

DB	Citing
Web of science	12
Scopus	10
Elibrary	12