Abstract: The selectivity of nickel catalysts in butadiene hydrogenation depends on the nature of the crystallographic planes accessible to reactants and on the electron state of a metal, which is stipulated by the morphology of their particles. Selective hydrogenation to butenes occurs on Ni(110), whereas complete hydrogenation occurs on Ni(111) and Ni(100). Catalytic properties of individual crystallographic planes of nickel in hydrogenation at a normal pressure were qualitatively evaluated for the first time.

Cite: Molchanov V.V. , Chesnokov V.V. , Buyanov R.A. , Zaitseva N.A. , Zaikovskii V.I. , Plyasova L.M. , Bukhtiyarov V.I. , Prosvirin I.P. , Novgorodov B.N.
New Metal-Carbon Catalysts: II. The Origin of Selectivity of Nickel Catalysts in Hydrogenation Reactions
Kinetics and Catalysis. 1998. V.39. N3. P.386-391. WOS Scopus РИНЦ ANCAN

Original: Молчанов В.В. , Чесноков В.В. , Буянов Р.А. , Зайцева Н.А. , Зайковский В.И. , Плясова Л.М. , Бухтияров В.И. , Просвирин И.П. , Новгородов Б.Н.
Новые металл-углеродные катализаторы. II. Причины селективного действия никелевых катализаторов в реакциях гидрирования
Кинетика и катализ. 1998. Т.39. №3. С.416-421. РИНЦ

Dates:

Submitted:

Oct 30, 1995

Identifiers:

Web of science:	WOS:000076097900014
Scopus:	2-s2.0-0042393426
Elibrary:	13279187
Chemical Abstracts:	1998:653496
Chemical Abstracts (print):	129:302302

Citing:

DB	Citing
Web of science	9
Scopus	8
Elibrary	10