Реферат: Dynamics of isotopic label transfer in open catalytic systems is studied in the general form. The advantages and limitations of steady-state isotopic transient kinetic analysis are compared to those of the kinetic relaxation method. The applicability of the isotopic relaxation method to the discrimination of the reaction mechanisms is discussed. This method can also be applied to the determination of the composition of adsorption layer and kinetic parameters taking into account gas dynamics in a catalytic reactor. The mechanism of isotopic label transfer in ethylene epoxidation over silver catalyst is elucidated. The surface coverages by various forms of adsorbed oxygen and the values of rate constants of the steps of ethylene oxide and carbon dioxide formation are estimated.

Библиографическая ссылка: Sadovskaya E.M. , Bulushev D.A. , Balʹzhinimaev B.S.
Dynamics of Isotopic Label Transfer in Catalytic Reactions
Kinetics and Catalysis. 1999. V.40. N1. P.54-61. WOS Scopus РИНЦ CAPlusCA

Оригинальная: Садовская Е.М. , Булушев Д.А. , Бальжинимаев Б.С.
Исследование динамики переноса изотопной метки в каталитических реакциях
Кинетика и катализ. 1999. Т.40. №1. С.61-69. РИНЦ

Даты:

Поступила в редакцию:

23 июн. 1997 г.

Идентификаторы БД:

Web of science:	WOS:000078894900008
Scopus:	2-s2.0-0002768093
РИНЦ:	13325566
Chemical Abstracts:	1999:176402
Chemical Abstracts (print):	130:281683

Цитирование в БД:

БД	Цитирований
Web of science	17
Scopus	14
РИНЦ	18