Kinetics and Mechanism of Water Catalytic Oxidation by a Ru3+(bpy)3 Complex in the Presence of Colloidal Cobalt Hydroxide Full article
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Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2000, Volume: 41, Number: 3, Pages: 340-348 Pages count : 9 DOI: 10.1007/BF02755370 | ||
| Tags | Kinetic Curve; Borate Buffer; Catalyst Concentration; Bipyridyl; Ruthenium Complex | ||
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Abstract:
Kinetics of the catalytic oxidation of water to molecular oxygen by a tris(bipyridyl) Ru(III) complex is studied in the presence of colloidal cobalt hydroxide stabilized by starch. Oxidant consumption follows the first-order rate law with respect to the oxidant concentration. The dependence of the apparent rate constant of this process on the catalyst concentration, initial oxidant concentration, and initial concentration of its reduced form was determined. The dependence of the oxygen yield on H+ at pH 7–11 and a catalyst concentration of 10-7-10-3 mol/l is studied. An intermediate product of the reaction was found, which is probably a bridged peroxo complex of cobalt. The kinetic scheme and mechanism of the reaction is proposed, which agree with experimental observations.
Cite:
Pestunova O.P.
, Elizarova G.L.
, Parmon V.N.
Kinetics and Mechanism of Water Catalytic Oxidation by a Ru3+(bpy)3 Complex in the Presence of Colloidal Cobalt Hydroxide
Kinetics and Catalysis. 2000. V.41. N3. P.340-348. DOI: 10.1007/BF02755370 WOS Scopus РИНЦ ANCAN OpenAlex
Kinetics and Mechanism of Water Catalytic Oxidation by a Ru3+(bpy)3 Complex in the Presence of Colloidal Cobalt Hydroxide
Kinetics and Catalysis. 2000. V.41. N3. P.340-348. DOI: 10.1007/BF02755370 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Пестунова О.П.
, Елизарова Г.Л.
, Пармон В.Н.
Кинетика и механизм каталитического окисления воды комплексом Ru3+(bpy)3 в присутствии коллоидного гидроксида кобальта
Кинетика и катализ. 2000. Т.41. №3. С.375-384. РИНЦ
Кинетика и механизм каталитического окисления воды комплексом Ru3+(bpy)3 в присутствии коллоидного гидроксида кобальта
Кинетика и катализ. 2000. Т.41. №3. С.375-384. РИНЦ
Dates:
| Submitted: | Nov 13, 1998 |
| Published print: | May 1, 2000 |
Identifiers:
| Web of science: | WOS:000088248600008 |
| Scopus: | 2-s2.0-0008361795 |
| Elibrary: | 13338002 |
| Chemical Abstracts: | 2000:521910 |
| Chemical Abstracts (print): | 133:110523 |
| OpenAlex: | W1982856317 |