Liquid-Phase Hydrogenation of Thiophenes on Palladium Sulfide Catalysts | Sciact - CRIS-system of Boreskov Institute of Catalysis

Liquid-Phase Hydrogenation of Thiophenes on Palladium Sulfide Catalysts Full article

Journal

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Output data

Year: 2000, Volume: 41, Number: 3, Pages: 388-393 Pages count : 6 DOI: 10.1007/BF02755377

Tags

Thiophene; Hydrogen Sulfide; Dodecane; Carbon Support; Benzothiophene

Authors

Zirka A.A. ¹ , Mashkina A.V. ¹

Affiliations

1	Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, 630090, Novosibirsk, Russia

Palladium sulfide catalysts are active for the hydrogenation of thiophenes of different structure in hydrocarbons at 220-300 °С and 3.0-9.5 MPa. Thiophenes and benzothiophenes are close in reactivity. An increase in palladium sulfide concentration in the catalyst leads to an increase in the reaction rate per 1 g of the catalyst but has only a slight effect on the specific reaction rate of hydrogenation calculated per 1 g of Pd. The specific activity of palladium sulfide supported on aluminosilicate is one order of magnitude higher than that of PdS without a support and the catalysts supported on the aluminum oxide and carbon. The aluminosilicate-supported catalyst is also more selective.

Zirka A.A. , Mashkina A.V.
Liquid-Phase Hydrogenation of Thiophenes on Palladium Sulfide Catalysts
Kinetics and Catalysis. 2000. V.41. N3. P.388-393. DOI: 10.1007/BF02755377 WOS Scopus РИНЦ ANCAN OpenAlex

Зирка А.А. , Машкина А.В.
Жидкофазное гидрирование тиофенов в присутствии сульфидпалладиевых катализаторов
Кинетика и катализ. 2000. Т.41. №3. С.426-432. РИНЦ

Submitted:	Oct 30, 1998
Published print:	May 1, 2000

Web of science:	WOS:000088248600015
Scopus:	2-s2.0-0034190111
Elibrary:	13338454
Chemical Abstracts:	2000:521917
Chemical Abstracts (print):	133:119954
OpenAlex:	W2077850236

DB	Citing
Web of science	10
Scopus	9
Elibrary	10
OpenAlex	9