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Activity of Palladium Sulfide Catalysts in the Reaction of Gas-Phase Hydrogenation of 2-Methylthiophene Full article

Journal Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Output data Year: 2000, Volume: 41, Number: 4, Pages: 521-526 Pages count : 6 DOI: 10.1007/BF02756069
Tags Palladium; Thiophene; Thiophene Ring; Organosulfur Compound; Sulfide Catalyst
Authors Mashkina A.V. 1 , Zirka A.A. 1
Affiliations
1 Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, 630090, Novosibirsk, Russia

Abstract: In the interaction of hydrogen with 2-methylthiophene in the gas phase over palladium sulfide catalysts at 180–260°С and 0.1–0.8 MPa, the saturation of the thiophene ring resulting in 2-methylthiolane and the hydrogenolysis of 2-methylthiophene occurs. When the conversion is lower than 60%, these reactions occur independently; at higher conversions, methylthiolane also undergoes hydrogenolysis. The specific catalytic activity of PdS supported on γ-Al2O3, TiO2, and carbon and without support is much lower in the hydrogenation of 2-methylthiophene than the activity of PdS supported on SiO2, aluminosilicate, and zeolite HNaY having strong Brönsted acid surface sites.
Cite: Mashkina A.V. , Zirka A.A.
Activity of Palladium Sulfide Catalysts in the Reaction of Gas-Phase Hydrogenation of 2-Methylthiophene
Kinetics and Catalysis. 2000. V.41. N4. P.521-526. DOI: 10.1007/BF02756069 WOS Scopus РИНЦ ANCAN OpenAlex
Original: Машкина А.В. , Зирка А.А.
Активность сульфидпалладиевых катализаторов в реакции газофазного гидрирования 2-метилтиофена
Кинетика и катализ. 2000. Т.41. №4. С.575-581. РИНЦ
Dates:
Submitted: Nov 13, 1998
Published print: Jul 1, 2000
Identifiers:
Web of science: WOS:000089026100012
Scopus: 2-s2.0-0034233117
Elibrary: 13350794
Chemical Abstracts: 2000:656038
Chemical Abstracts (print): 133:240372
OpenAlex: W2068164906
Citing:
DB Citing
Web of science 13
Scopus 9
Elibrary 16
OpenAlex 8
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