Activity of Palladium Sulfide Catalysts in the Reaction of Gas-Phase Hydrogenation of 2-Methylthiophene Full article
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Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2000, Volume: 41, Number: 4, Pages: 521-526 Pages count : 6 DOI: 10.1007/BF02756069 | ||
| Tags | Palladium; Thiophene; Thiophene Ring; Organosulfur Compound; Sulfide Catalyst | ||
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Abstract:
In the interaction of hydrogen with 2-methylthiophene in the gas phase over palladium sulfide catalysts at 180–260°С and 0.1–0.8 MPa, the saturation of the thiophene ring resulting in 2-methylthiolane and the hydrogenolysis of
2-methylthiophene occurs. When the conversion is lower than 60%, these reactions occur independently; at higher conversions, methylthiolane also undergoes hydrogenolysis. The specific catalytic activity of PdS supported on γ-Al2O3, TiO2, and carbon and without support is much lower in the hydrogenation of 2-methylthiophene than the activity of PdS supported on SiO2, aluminosilicate, and zeolite HNaY having strong Brönsted acid surface sites.
Cite:
Mashkina A.V.
, Zirka A.A.
Activity of Palladium Sulfide Catalysts in the Reaction of Gas-Phase Hydrogenation of 2-Methylthiophene
Kinetics and Catalysis. 2000. V.41. N4. P.521-526. DOI: 10.1007/BF02756069 WOS Scopus РИНЦ ANCAN OpenAlex
Activity of Palladium Sulfide Catalysts in the Reaction of Gas-Phase Hydrogenation of 2-Methylthiophene
Kinetics and Catalysis. 2000. V.41. N4. P.521-526. DOI: 10.1007/BF02756069 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Машкина А.В.
, Зирка А.А.
Активность сульфидпалладиевых катализаторов в реакции газофазного гидрирования 2-метилтиофена
Кинетика и катализ. 2000. Т.41. №4. С.575-581. РИНЦ
Активность сульфидпалладиевых катализаторов в реакции газофазного гидрирования 2-метилтиофена
Кинетика и катализ. 2000. Т.41. №4. С.575-581. РИНЦ
Dates:
| Submitted: | Nov 13, 1998 |
| Published print: | Jul 1, 2000 |
Identifiers:
| Web of science: | WOS:000089026100012 |
| Scopus: | 2-s2.0-0034233117 |
| Elibrary: | 13350794 |
| Chemical Abstracts: | 2000:656038 |
| Chemical Abstracts (print): | 133:240372 |
| OpenAlex: | W2068164906 |