Ammoxidation of Methylpyrazine over Binary Oxide Systems: IV. A Vanadia-Titania System Full article
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
||
---|---|---|---|
Output data | Year: 2000, Volume: 41, Number: 5, Pages: 670-678 Pages count : 9 DOI: 10.1007/BF02754566 | ||
Tags | Pyrazine; Carbon Oxide; Ammoxidation; Differential Dissolution; Binary Sample | ||
Authors |
|
||
Affiliations |
|
Funding (3)
1 | Russian Foundation for Basic Research | 96-03-33087 |
2 | Russian Foundation for Basic Research | 98-03-32323 |
3 | International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union | IR-97-0059 |
Abstract:
The catalytic properties of vanadia-titania catalysts in methylpyrazine ammoxidation are studied. The activity monotonically increases on changing the concentration from pure titania to pure vanadia, and the yield of methylpyrazine passes through a broad maximum corresponding to a V2O5 concentration from 10 to 75 wt %. The active sites of binary catalysts contain V5+ cations in a substantially distorted octahedral environment of oxygen atoms, which are strongly bound to anatase, likely due to the formation of V-O-Ti bonds
Cite:
Bondareva V.M.
, Andrushkevich T.V.
, Lapina O.B.
, Malakhov V.V.
, Dovlitova L.S.
, Vlasov A.A.
Ammoxidation of Methylpyrazine over Binary Oxide Systems: IV. A Vanadia-Titania System
Kinetics and Catalysis. 2000. V.41. N5. P.670-678. DOI: 10.1007/BF02754566 WOS Scopus РИНЦ ANCAN OpenAlex
Ammoxidation of Methylpyrazine over Binary Oxide Systems: IV. A Vanadia-Titania System
Kinetics and Catalysis. 2000. V.41. N5. P.670-678. DOI: 10.1007/BF02754566 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Бондарева В.М.
, Андрушкевич Т.В.
, Лапина О.Б.
, Малахов В.В.
, Довлитова Л.С.
, Власов А.А.
Окислительный аммонолиз метилпиразина на бинарных оксидных системах. IV. Ванадийтитановая система
Кинетика и катализ. 2000. Т.41. №5. С.736-744. РИНЦ
Окислительный аммонолиз метилпиразина на бинарных оксидных системах. IV. Ванадийтитановая система
Кинетика и катализ. 2000. Т.41. №5. С.736-744. РИНЦ
Dates:
Submitted: | Apr 7, 1999 |
Published print: | Sep 1, 2000 |
Published online: | Sep 1, 2000 |
Identifiers:
Web of science: | WOS:000165147300012 |
Scopus: | 2-s2.0-0034279149 |
Elibrary: | 13349032 |
Chemical Abstracts: | 2000:791250 |
Chemical Abstracts (print): | 134:71237 |
OpenAlex: | W2913367105 |