Preparation of Polyoxometalate-Stabilized Colloidal Solutions of Palladium Metal and Catalysts Supported on Them Full article
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2000, Volume: 41, Number: 6, Pages: 844-852 Pages count : 9 DOI: 10.1023/A:1026641607471 | ||||
| Tags | Physical Chemistry; Palladium; Cluster Size; Individual Particle; Colloidal Solution | ||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Russian Foundation for Basic Research | 96-15-97557 |
| 2 | The Ministry of Education and Science of the Russian Federation | 3N-107-96 |
Abstract:
Sols containing Pd(0) clusters with polyoxo anions are prepared by the reduction of colloidal solutions of polyhydroxo complexes of Pd(II) in the presence of Mo(VI), W(VI), V(V), and Nb(V) polyoxo anions. The cluster sizes varied within the limits of 1–10 nm depending on the nature of the polyoxo anion. The stability of sols toward coagulation depends on the ratio between the palladium and polyoxo anion amounts in solution and on the composition of the solvent. Supported Pd catalysts are obtained by the adsorption of particles from sols; Pd can exist in these catalysts as individual particles or associates or form filamentary structures.
Cite:
Maksimov G.M.
, Zaikovskii V.I.
, Matveev K.I.
, Likholobov V.A.
Preparation of Polyoxometalate-Stabilized Colloidal Solutions of Palladium Metal and Catalysts Supported on Them
Kinetics and Catalysis. 2000. V.41. N6. P.844-852. DOI: 10.1023/A:1026641607471 WOS Scopus РИНЦ ANCAN OpenAlex
Preparation of Polyoxometalate-Stabilized Colloidal Solutions of Palladium Metal and Catalysts Supported on Them
Kinetics and Catalysis. 2000. V.41. N6. P.844-852. DOI: 10.1023/A:1026641607471 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Максимов Г.М.
, Зайковский В.И.
, Матвеев К.И.
, Лихолобов В.А.
Получение коллоидных растворов металлического Pd, стабилизированных полиоксометаллатами, и нанесенных катализаторов на их основе
Кинетика и катализ. 2000. Т.41. №6. С.925-932. РИНЦ
Получение коллоидных растворов металлического Pd, стабилизированных полиоксометаллатами, и нанесенных катализаторов на их основе
Кинетика и катализ. 2000. Т.41. №6. С.925-932. РИНЦ
Dates:
| Submitted: | Jun 4, 1999 |
| Published print: | Nov 1, 2000 |
Identifiers:
| Web of science: | WOS:000166250600021 |
| Scopus: | 2-s2.0-0043282234 |
| Elibrary: | 13344444 |
| Chemical Abstracts: | 2001:30624 |
| Chemical Abstracts (print): | 134:198602 |
| OpenAlex: | W246501068 |