Kinetics of Pinane Oxidation to Pinane Hydroperoxide by Dioxygen | Sciact - CRIS-system of Boreskov Institute of Catalysis

Kinetics of Pinane Oxidation to Pinane Hydroperoxide by Dioxygen Full article

Journal

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Output data

Year: 2001, Volume: 42, Number: 1, Pages: 41-45 Pages count : 5 DOI: 10.1023/A:1004896512191

Tags

Oxidation; Physical Chemistry; Free Radical; Hydroperoxide; Dioxygen

Authors

Ilʹina I.I. ¹ , Simakova I.L. ¹ , Semikolenov V.A. ¹

Affiliations

1	Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk, 630090 Russia

The liquid-phase oxidation of pinane to pinane hydroperoxide (PHP) by dioxygen is studied at 353–373 K and under dioxygen pressures ranging from 2 to 4 atm. The rate of pinane oxidation is described by the equation w = wO2 + wPHP , where the term wO2 is independent of the PHP concentration, wPHP is a function of the concentration [PHP]n, and n ranges from 0.5 at low [PHP] to 1.0 at high [PHP]. The cis-isomer of 2-hydroperoxopinane generates free radicals during autooxidation. The ratio of the rate constants of cis- and trans-pinane oxidation is found (kcis /ktrans = 4.0). The selectivity of the oxidation of pinane to PHP can reach 90–95%.

Ilʹina I.I. , Simakova I.L. , Semikolenov V.A.
Kinetics of Pinane Oxidation to Pinane Hydroperoxide by Dioxygen
Kinetics and Catalysis. 2001. V.42. N1. P.41-45. DOI: 10.1023/A:1004896512191 WOS Scopus РИНЦ ANCAN OpenAlex

Ильина И.И. , Симакова И.Л. , Семиколенов В.А.
Кинетические закономерности окисления пинана в гидропероксид пинана молекулярным кислородом
Кинетика и катализ. 2001. Т.42. №1. С.48-52. РИНЦ

Submitted:	Jan 10, 2000
Published print:	Jan 1, 2001

Web of science:	WOS:000167426200005
Scopus:	2-s2.0-0037563945
Elibrary:	13388611
Chemical Abstracts:	2001:204696
Chemical Abstracts (print):	134:366490
OpenAlex:	W1591943462

DB	Citing
Web of science	6
Scopus	6
Elibrary	3
OpenAlex	5