Nonstationary Phenomena in the Low-Temperature Gas-Phase Catalytic Oxidation of H2S with Oxygen Full article
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2001, Volume: 42, Number: 5, Pages: 657-661 Pages count : 5 DOI: 10.1023/A:1012319614113 | ||
| Tags | Oxidation; Oxygen; Sulfur; Physical Chemistry; Catalyst Surface | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Foundation for Basic Research | 98-03-32312 |
Abstract:
The conditions of the existence were determined and reasons were revealed for the appearance of periodic oscillations of the SO2 concentration in the reaction products and warming temperature in the catalyst bed in the oxidation of H2S with oxygen at temperatures below the dew point of sulfur on the V–Al–Ti oxide catalyst. The formation of polysulfides during the reaction was experimentally found. It was proposed that the adsorption of sulfur and polysulfides on the catalyst surface is responsible for the observed oscillatory processes.
Cite:
Kovalenko O.N.
, Kundo N.
, Novopashina V.M.
, Kalinkin P.N.
Nonstationary Phenomena in the Low-Temperature Gas-Phase Catalytic Oxidation of H2S with Oxygen
Kinetics and Catalysis. 2001. V.42. N5. P.657-661. DOI: 10.1023/A:1012319614113 WOS Scopus РИНЦ ANCAN OpenAlex
Nonstationary Phenomena in the Low-Temperature Gas-Phase Catalytic Oxidation of H2S with Oxygen
Kinetics and Catalysis. 2001. V.42. N5. P.657-661. DOI: 10.1023/A:1012319614113 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Коваленко О.Н.
, Кундо Н.Н.
, Новопашина В.М.
, Калинкин П.Н.
Нестационарные явления при низкотемпературном газофазном каталитическом окислении H2S кислородом
Кинетика и катализ. 2001. Т.42. №5. С.724-729. РИНЦ
Нестационарные явления при низкотемпературном газофазном каталитическом окислении H2S кислородом
Кинетика и катализ. 2001. Т.42. №5. С.724-729. РИНЦ
Dates:
| Submitted: | Dec 22, 1999 |
| Published print: | Sep 1, 2001 |
Identifiers:
| Web of science: | WOS:000171974100011 |
| Scopus: | 2-s2.0-0037563750 |
| Elibrary: | 13376456 |
| Chemical Abstracts: | 2001:815698 |
| Chemical Abstracts (print): | 136:171772 |
| OpenAlex: | W36814482 |