Kinetics of 2-Pinanol Isomerization to Linalool on the Monolith Carbon-Containing Catalyst | Sciact - CRIS-system of Boreskov Institute of Catalysis

Kinetics of 2-Pinanol Isomerization to Linalool on the Monolith Carbon-Containing Catalyst Full article

Journal

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Output data

Year: 2001, Volume: 42, Number: 5, Pages: 686-692 Pages count : 7 DOI: 10.1023/A:1012379800000

Tags

Oxidation; Oxygen; Sulfur; Physical Chemistry; Catalyst Surface

Authors

Ilʹina I.I. ¹ , Simakova I.L. ¹ , Semikolenov V.A. ¹

Affiliations

1	Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk, 630090 Russia

Isomerization of 2-pinanol into linalool is studied on a monolith carbon-containing catalyst at 733–893 and a total pressure of 2–40 torr. The rate constants of cis(trans)-2-pinanol transformation into linalool and linalool cyclization are determined. Experimental data are described by the consecutive kinetic scheme. The mechanism of linalool formation is proposed according to which pinane ring opening occurs in an intramolecular reaction. A highly selective process of linalool synthesis by the thermal isomerization of 2-pinanol is shown to be possible.

Ilʹina I.I. , Simakova I.L. , Semikolenov V.A.
Kinetics of 2-Pinanol Isomerization to Linalool on the Monolith Carbon-Containing Catalyst
Kinetics and Catalysis. 2001. V.42. N5. P.686-692. DOI: 10.1023/A:1012379800000 WOS Scopus РИНЦ ANCAN OpenAlex

Ильина И.И. , Симакова И.Л. , Семиколенов В.А.
Кинетические закономерности изомеризации пинан-2-ола в линалоол на блочном углеродсодержащем катализаторе
Кинетика и катализ. 2001. Т.42. №5. С.754-761. РИНЦ

Submitted:	Sep 27, 2000
Published print:	Sep 1, 2001

Web of science:	WOS:000171974100016
Scopus:	2-s2.0-0037563738
Elibrary:	13376455
Chemical Abstracts:	2001:815703
Chemical Abstracts (print):	136:85952
OpenAlex:	W109338375

DB	Citing
Web of science	2
Scopus	4
Elibrary	4
OpenAlex	4