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Catalysts Based on Fiberglass Supports: III. Properties of Supported Metals (Pt and Pd) According to Electron-Microscopic and XPS Data Full article

Journal Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Output data Year: 2001, Volume: 42, Number: 6, Pages: 837-846 Pages count : 10 DOI: 10.1023/A:1013291418524
Tags Soda; Physical Chemistry; Outer Surface; Metal Particle; Fiberglass
Authors Simonova L.G. 1 , Barelko V.V. 2 , Toktarev A.V. 1 , Zaikovskii V.I. 1 , Bukhtiyarov V.I. 1 , Kaichev V.V. 1 , Balʹzhinimaev B.S. 1
Affiliations
1 Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk, 630090 Russia
2 Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432 Russia

Funding (1)

1 North Atlantic Treaty Organization SfP-971897

Abstract: Under various preparation conditions, metals supported on leached borosilicate and soda–silica fiberglass form three types of particles. First, these are metal particles in sizes from tens to hundreds of angstrom distributed over the outer surface of fibers. Second, in the presence of mesopores in fiberglass supports (borosilicate glasses), metal particles of commensurable sizes (15–100 Å) are localized in the cavities. Third, dispersed (<10 Å) particles are present in the bulk of fiberglass; these particles are intercalated into the bulk of leached glasses as deep as several hundreds of angstrom. The amount of a metal and the depth of penetration into the bulk of fiberglass can be controlled by preparation conditions and by the addition of cointercalates, which are responsible for pillaring effects.
Cite: Simonova L.G. , Barelko V.V. , Toktarev A.V. , Zaikovskii V.I. , Bukhtiyarov V.I. , Kaichev V.V. , Balʹzhinimaev B.S.
Catalysts Based on Fiberglass Supports: III. Properties of Supported Metals (Pt and Pd) According to Electron-Microscopic and XPS Data
Kinetics and Catalysis. 2001. V.42. N6. P.837-846. DOI: 10.1023/A:1013291418524 WOS Scopus РИНЦ ANCAN OpenAlex
Original: Симонова Л.Г. , Барелко В.В. , Токтарев А.В. , Зайковский В.И. , Бухтияров В.И. , Каичев В.В. , Бальжинимаев Б.С.
Катализаторы на основе стекловолокнистых носителей. III. Свойства нанесенных металлов (Pt, Pd) по данным электронной микроскопии и РФЭС
Кинетика и катализ. 2001. Т.42. №6. С.917-927. РИНЦ
Dates:
Submitted: Mar 13, 2000
Published print: Nov 1, 2001
Identifiers:
Web of science: WOS:000173018500018
Scopus: 2-s2.0-0038578062
Elibrary: 13366000
Chemical Abstracts: 2002:30751
Chemical Abstracts (print): 136:59288
OpenAlex: W281852751
Citing:
DB Citing
Web of science 14
Scopus 14
Elibrary 17
OpenAlex 13
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