Kinetics of the Hydrogenation of Pinane Hydroperoxide to Pinanol on Pd/C Научная публикация
| Журнал |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
||
|---|---|---|---|
| Вых. Данные | Год: 2002, Том: 43, Номер: 5, Страницы: 652-656 Страниц : 5 DOI: 10.1023/A:1020691626999 | ||
| Ключевые слова | Hydrogenation; Physical Chemistry; Hydroperoxide; High Selectivity; Mild Condition | ||
| Авторы |
|
||
| Организации |
|
Реферат:
The liquid-phase hydrogenation of pinane hydroperoxide (PHP) to pinanol on a Pd/C catalyst at 20–80°C and hydrogen pressures of 1–11 atm was studied. It was found that the rate of hydrogenation decreased with PHP concentration. The rate of PHP hydrogenation dramatically increased as the pressure of hydrogen was increased in a range of 2.5–3 atm. A mechanism was proposed for the hydrogenation of PHP. According to this mechanism, the step of hydrogen activation (homolytic or heterolytic addition) depends on the redox properties of the catalyst surface (the ratio between adsorbed PHP species and H2). It was found that pinanol can be prepared with high selectivity by the hydrogenation of PHP on a Pd/C catalyst under mild conditions.
Библиографическая ссылка:
Ilʹina I.I.
, Simakova I.L.
, Semikolenov V.A.
Kinetics of the Hydrogenation of Pinane Hydroperoxide to Pinanol on Pd/C
Kinetics and Catalysis. 2002. V.43. N5. P.652-656. DOI: 10.1023/A:1020691626999 WOS Scopus РИНЦ OpenAlex CAPlusCA
Kinetics of the Hydrogenation of Pinane Hydroperoxide to Pinanol on Pd/C
Kinetics and Catalysis. 2002. V.43. N5. P.652-656. DOI: 10.1023/A:1020691626999 WOS Scopus РИНЦ OpenAlex CAPlusCA
Оригинальная:
Ильина И.И.
, Симакова И.Л.
, Семиколенов В.А.
Кинетические закономерности гидрирования гидропероксида пинана в пинанол на Pd/C
Кинетика и катализ. 2002. Т.43. №5. С.699-703. РИНЦ
Кинетические закономерности гидрирования гидропероксида пинана в пинанол на Pd/C
Кинетика и катализ. 2002. Т.43. №5. С.699-703. РИНЦ
Даты:
| Поступила в редакцию: | 10 янв. 2000 г. |
| Опубликована в печати: | 1 сент. 2002 г. |
Идентификаторы БД:
| ≡ Web of science: | WOS:000179128700004 |
| ≡ Scopus: | 2-s2.0-0037968177 |
| ≡ РИНЦ: | 13391320 |
| ≡ OpenAlex: | W9292394 |
| ≡ Chemical Abstracts: | 2002:786597 |
| ≡ Chemical Abstracts (print): | 138:89930 |