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Structural Arrangement of Fe–Sb–O Catalysts Full article

Journal Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Output data Year: 2002, Volume: 43, Number: 5, Pages: 731-735 Pages count : 5 DOI: 10.1023/A:1020616432451
Tags Oxide; Oxygen; Iron; Physical Chemistry; Structural Change
Authors Zenkovets G.A. 1 , Kryukova G.N. 1 , Tsybulya S.V. 1
Affiliations
1 Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk, 630090 Russia

Abstract: In iron–antimony catalysts containing excess antimony oxide and consisting of a mixture of FeSbO4 and α-Sb2O4 phases, the structure of iron antimonate changes compared to the catalyst with an equimolar composition, which is the pure FeSbO4 phase. In the presence of excess antimony oxide in the near-surface layer of iron antimonate, extended defects with a structure of crystallographic shift are formed. These accumulate overstoichiometric antimony. Such a structural change is associated with changes in the acid–base properties and the surface oxygen binding strength.
Cite: Zenkovets G.A. , Kryukova G.N. , Tsybulya S.V.
Structural Arrangement of Fe–Sb–O Catalysts
Kinetics and Catalysis. 2002. V.43. N5. P.731-735. DOI: 10.1023/A:1020616432451 WOS Scopus РИНЦ ANCAN OpenAlex
Original: Зенковец Г.А. , Крюкова Г.Н. , Цыбуля С.В.
Структурное устройство Fe-Sb-O-катализаторов
Кинетика и катализ. 2002. Т.43. №5. С.783-787. РИНЦ
Dates:
Submitted: Feb 15, 2002
Published print: Sep 1, 2002
Identifiers:
Web of science: WOS:000179128700016
Scopus: 2-s2.0-0037900647
Elibrary: 13397872
Chemical Abstracts: 2002:786609
Chemical Abstracts (print): 137:389637
OpenAlex: W147301952
Citing:
DB Citing
Web of science 3
Scopus 3
Elibrary 2
OpenAlex 3
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