Reactivity of the Peroxo Complexes of Copper(II) Hydroxide | Sciact - CRIS-system of Boreskov Institute of Catalysis

Reactivity of the Peroxo Complexes of Copper(II) Hydroxide Full article

Journal

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Output data

Year: 2003, Volume: 44, Number: 2, Pages: 211-220 Pages count : 10 DOI: 10.1023/A:1023352412121

Tags

Oxidation; Copper; Ammonia; Physical Chemistry; H2O2

Authors

Elizarova G.L. ¹ , Odegova G.V. ¹ , Matvienko L.G. ¹ , Talsi E.P. ¹ , Kolomiichuk V.N. ¹ , Parmon V.N. ¹

Affiliations

1	Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk, 630090 Russia

In the interaction with H2O2 in an alkaline medium, Cu(OH)2 forms terminal Cu–OOH and bridging peroxo complexes with the μ-1,1 and μ-η2:η2 structures. It was found that the terminal peroxide is active in the reactions of H2O2 decomposition, diphenol oxidation, and nitrile conversion into acid amides. The promoting effect of ammonia on these reactions was found. A possible mechanism is discussed.

Elizarova G.L. , Odegova G.V. , Matvienko L.G. , Talsi E.P. , Kolomiichuk V.N. , Parmon V.N.
Reactivity of the Peroxo Complexes of Copper(II) Hydroxide
Kinetics and Catalysis. 2003. V.44. N2. P.211-220. DOI: 10.1023/A:1023352412121 WOS Scopus РИНЦ ANCAN OpenAlex

Елизарова Г.Л. , Одегова Г.В. , Матвиенко Л.Г. , Талзи Е.П. , Коломийчук В.Н. , Пармон В.Н.
Реакционная способность пероксокомплексов гидроксида меди (II)
Кинетика и катализ. 2003. Т.44. №2. С.227-236. РИНЦ

Submitted:	Dec 26, 2001
Published print:	Mar 1, 2003

Web of science:	WOS:000182774300007
Scopus:	2-s2.0-0037832710
Elibrary:	13441189
Chemical Abstracts:	2003:290163
Chemical Abstracts (print):	139:58651
OpenAlex:	W1485614440

DB	Citing
Web of science	8
Scopus	6
Elibrary	6
OpenAlex	10