Hydrodechlorination of Tetrachloromethane in the Vapor Phase in the Presence of Pd–Fe/Sibunit Catalysts Full article
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2004, Volume: 45, Number: 2, Pages: 183-188 Pages count : 6 DOI: 10.1023/B:KICA.0000023789.28190.1b | ||||
| Tags | Physical Chemistry; Hydrocarbon; Paraffin; High Stability; CCl4 | ||||
| Authors |
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| Affiliations |
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Funding (3)
| 1 | Russian Foundation for Basic Research | 01-03-33127 |
| 2 | Haldor Topsoe A/S | |
| 3 | International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union | 2000-00710 |
Abstract:
The hydrodechlorination of CCl4 in the presence of Pd–Fe/Sibunit catalysts of different composition was studied. An optimum concentration of the metals (2.5% at the ratio Pd/Fe = 1 : 4) was determined, which corresponds to the highest stability of catalysts and selectivity of C2–C4 olefin and paraffin formation. With the use of TPR and magnetic measurements, it was found that the metals occurred in an oxidized state in the course of the reaction; it is likely that this resulted in the formation of C2–C4 hydrocarbons.
Cite:
Golubina E.V.
, Lokteva E.S.
, Lazareva T.S.
, Kostyuk B.G.
, Lunin V.V.
, Simagina V.I.
, Stoyanova I.V.
Hydrodechlorination of Tetrachloromethane in the Vapor Phase in the Presence of Pd–Fe/Sibunit Catalysts
Kinetics and Catalysis. 2004. V.45. N2. P.183-188. DOI: 10.1023/B:KICA.0000023789.28190.1b WOS Scopus РИНЦ ANCAN OpenAlex
Hydrodechlorination of Tetrachloromethane in the Vapor Phase in the Presence of Pd–Fe/Sibunit Catalysts
Kinetics and Catalysis. 2004. V.45. N2. P.183-188. DOI: 10.1023/B:KICA.0000023789.28190.1b WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Голубина Е.В.
, Локтева Е.С.
, Лазарева Т.С.
, Костюк Б.Г.
, Лунин В.В.
, Симагина В.И.
, Стоянова И.В.
Гидродехлорирование тетрахлорметана в паровой фазе в присутствии катализаторов Pd-Fe/Сибунит
Кинетика и катализ. 2004. Т.45. №2. С.199-204. РИНЦ
Гидродехлорирование тетрахлорметана в паровой фазе в присутствии катализаторов Pd-Fe/Сибунит
Кинетика и катализ. 2004. Т.45. №2. С.199-204. РИНЦ
Dates:
| Submitted: | Dec 25, 2002 |
| Published print: | Mar 1, 2004 |
Identifiers:
| Web of science: | WOS:000221291000004 |
| Scopus: | 2-s2.0-3543078684 |
| Elibrary: | 13470088 |
| Chemical Abstracts: | 2004:304519 |
| Chemical Abstracts (print): | 141:142120 |
| OpenAlex: | W1986266091 |