An EXAFS Study of the Amorphous Cuprum Hydroxide Full article
| Conference |
11th National Synchrotron Radiation Conference 09-12 Jul 1996 , Новосибирск |
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| Journal |
Nuclear Instruments and Methods in Physics Research Section A
ISSN: 0168-9002 |
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| Output data | Year: 1998, Volume: 405, Number: 2-3, Pages: 341-343 Pages count : 3 DOI: 10.1016/S0168-9002(97)00147-2 | ||
| Tags | Absorption spectroscopy; Adsorption; Amorphization; Amorphous materials; Molecular structure; pH effects; Silica; X ray spectroscopy | ||
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Abstract:
It was shown that for the bulk cuprum hydroxide the amorphisation is determined only by an excess of water without which the Cu(OH)2 presents in the crystal form only. In the case of the supported cuprum hydroxide, the amorphisation is achieved by stabilisation of the hydroxide particles on a high dispersed silica surface under low concentration of the cuprum ions, so that the sizes of the supported complexes are small. The data obtained suggests that the cuprum from dilute solution (4 × 10−3M) under low values of pH is adsorbed on the surface SiO2 as a polymer-like structure similar to that of Cu(OH)2 rather than as isolated ions. This inference is confirmed by previously obtained results on adsorption of Cu2+ on TiO2.
Cite:
Kriventsov V.V.
, Elizarova G.L.
, Kochubey D.I.
An EXAFS Study of the Amorphous Cuprum Hydroxide
Nuclear Instruments and Methods in Physics Research Section A. 1998. V.405. N2-3. P.341-343. DOI: 10.1016/S0168-9002(97)00147-2 WOS Scopus РИНЦ ANCAN OpenAlex
An EXAFS Study of the Amorphous Cuprum Hydroxide
Nuclear Instruments and Methods in Physics Research Section A. 1998. V.405. N2-3. P.341-343. DOI: 10.1016/S0168-9002(97)00147-2 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Published print: | Mar 11, 1998 |
| Published online: | Jun 19, 1998 |
Identifiers:
| Web of science: | WOS:000072660800037 |
| Scopus: | 2-s2.0-0032507105 |
| Elibrary: | 13290836 |
| Chemical Abstracts: | 1998:198343 |
| Chemical Abstracts (print): | 128:197188 |
| OpenAlex: | W2080037288 |