Catalytic Hydrodechlorination of Polychlorinated Aromatic Hydrocarbons | Sciact - CRIS-system of Boreskov Institute of Catalysis

Catalytic Hydrodechlorination of Polychlorinated Aromatic Hydrocarbons Full article

Conference

18th Symposium on Halogenated Environmental Organic Pollutants
17-21 Aug 1998 , Stockholm

Journal

Organohalogen Compounds
ISSN: 1026-4892

Output data

Year: 1997, Volume: 31, Pages: 330-335 Pages count : 6

Authors

Simagina V.I. ¹ , Yakovlev V.A. ¹ , Stoyanova I.V. ¹ , Likholobov V.A. ¹

Affiliations

1	Boreskov Institute of Catalysis, Pr. Acad. Lavrentieva, 5. Novosibirsk, 630090. Russia

Liq.-phase hydrodechlorination of PhCl, C6Cl6, and polychlorinated biphenyls with H2 on Pd/C, Ni/C, or Pd-Ni/C was studied at 20-70° and 1-50 atm. The catalysts were prepd. via support impregnation with metal salt soln., drying, thermal treatment, and subsequent treatment with NaBH4 as reducing agent. Pd/C and Pd-Ni/C showed the highest activity and dechlorinated efficiently polychlorinated arenes at 70°. Kinetic studies proved the hydrodechlorination of these compds. to be consecutive reactions.

Simagina V.I. , Yakovlev V.A. , Stoyanova I.V. , Likholobov V.A.
Catalytic Hydrodechlorination of Polychlorinated Aromatic Hydrocarbons
Organohalogen Compounds. 1997. V.31. P.330-335. РИНЦ ANCAN

Elibrary:	28934248
Chemical Abstracts:	1998:199838
Chemical Abstracts (print):	128:217139

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