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Hydrodechlorination of Polychlorinated Benzenes and Biphenyls in the Presence of the Bimetallic Catalysts on Carbon Supports Full article

Conference 18th Symposium on Halogenated Environmental Organic Pollutants
17-21 Aug 1998 , Stockholm
Journal Organohalogen Compounds
ISSN: 1026-4892
Output data Year: 1998, Volume: 36, Pages: 313-316 Pages count : 4
Authors Simagina V.I. 1 , Stoyanova I.V. 1 , Yakovlev V.A. 1 , Nosov A.M. 1 , Kryukova G.N. 1 , Likholobov V.A. 1
Affiliations
1 Boreskov Institute of Catalysis, Pr. Ak. Lavrentieva, 5, Novosibirsk, 630090, Russia

Abstract: Chlorobenzene, hexachlorobenzene, and the dielec. liq. Sovtol 10 (74 wt% polychlorobiphenyls and 26 w% 1,2,4-trichlorobenzene) were hydrodechlorinated with Ni- and Pd-catalysts. Pure Ni/C- and Pd/C-catalysts were used, as well as a mixt. of both catalysts, and Ni/C-catalysts promoted with either 2 or 10% of Pd. The activities of these catalysts in the hydrodechlorination of chlorobenzene under atm. H2-pressure and 20° are tabulated. The dechlorination degree of hexachlorobenzene and Sovtol 10 in the presence of Ni- and bimetallic Ni-Pd-catalysts at 50-60° and at H2-pressures of 20 or 50 atm are also given.
Cite: Simagina V.I. , Stoyanova I.V. , Yakovlev V.A. , Nosov A.M. , Kryukova G.N. , Likholobov V.A.
Hydrodechlorination of Polychlorinated Benzenes and Biphenyls in the Presence of the Bimetallic Catalysts on Carbon Supports
Organohalogen Compounds. 1998. V.36. P.313-316. РИНЦ ANCAN
Identifiers:
Elibrary: 28388191
Chemical Abstracts: 1998:791196
Chemical Abstracts (print): 130:115572
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