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Thermodynamics of Isomerization of Butylenes: Equilibrium Compositions Full article

Journal Petroleum Chemistry
ISSN: 0965-5441 , E-ISSN: 1531-8532
Output data Year: 2001, Volume: 41, Number: 2, Pages: 126-130 Pages count : 5
Tags alkene derivative; butylene derivative; unclassified drug
Authors Lavrenov A.V. 1 , Ostrovskii N.M. 1 , Demanov Y.K. 1
Affiliations
1 Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Omsk 644053, ul. Neftezavodskaya 54, Russian Federation

Abstract: The disagreement in the literature data on equilibrium concentrations in the mixture of butylenes was demonstrated, and their correct values were calculated. The temperature dependence for the equilibrium constant of the isomerization of n-butylenes into isobutylene was derived. It was shown that the product compositions achieved in the manufacture of isobutylene by the skeleton isomerization of n-butylenes can be close to the equilibrium ratios. The experimental results obtained on F/Al2O3 and Nb2O5/Al2O3 catalysts are given.
Cite: Lavrenov A.V. , Ostrovskii N.M. , Demanov Y.K.
Thermodynamics of Isomerization of Butylenes: Equilibrium Compositions
Petroleum Chemistry. 2001. V.41. N2. P.126-130. WOS Scopus РИНЦ
Original: Лавренов А.В. , Островский Н.М. , Деманов Ю.К.
Термодинамика изомеризации бутиленов. 1. Равновесные составы
Нефтехимия. 2001. Т.41. №2. С.144-148. Scopus РИНЦ ANCAN
Dates:
Submitted: Mar 21, 2000
Published print: Mar 1, 2001
Identifiers:
Web of science: WOS:000168338000009
Scopus: 2-s2.0-0035297140
Elibrary: 13375742
Citing:
DB Citing
Web of science 3
Scopus 3
Elibrary 3