Biphenyl Oxidation with Nitrous Oxide on MFI Zeolites Full article
| Journal |
Petroleum Chemistry
ISSN: 0965-5441 , E-ISSN: 1531-8532 |
||
|---|---|---|---|
| Output data | Year: 2004, Volume: 44, Number: 5, Pages: 322-327 Pages count : 6 | ||
| Tags | SELECTIVE OXIDATION; PHENOL OXIDATION; FeZSM-5 ZEOLITES; BENZENE; HYDROXYLATION; N2O; IRON; CATALYSTS; OXYGEN; SITES | ||
| Authors |
|
||
| Affiliations |
|
Abstract:
The gas-phase reaction of biphenyl oxidation with nitrous oxide on iron-containing zeolite MFI was studied. It was shown that the main products of this reaction were monosubstituted phenylphenols, which were represented predominantly by para- and meta-isomers. Optimal reaction conditions, ensuring a high selectivity for phenylphenols (similar to95%), were found. The initial catalyst productivity was similar to1.5 mmol of PhPhOH/(g h). The activity decreased in the course of the reaction as a result of catalyst deactivation by coking.
Cite:
Ivanov D.P.
, Pirutko L.V.
, Sobolev V.I.
Biphenyl Oxidation with Nitrous Oxide on MFI Zeolites
Petroleum Chemistry. 2004. V.44. N5. P.322-327. WOS Scopus РИНЦ
Biphenyl Oxidation with Nitrous Oxide on MFI Zeolites
Petroleum Chemistry. 2004. V.44. N5. P.322-327. WOS Scopus РИНЦ
Original:
Иванов Д.П.
, Пирютко Л.В.
, Соболев В.И.
Окисление дифенила закисью азота на цеолитах MFI
Нефтехимия. 2004. Т.44. №5. С.351-357. Scopus РИНЦ ANCAN
Окисление дифенила закисью азота на цеолитах MFI
Нефтехимия. 2004. Т.44. №5. С.351-357. Scopus РИНЦ ANCAN
Dates:
| Submitted: | Mar 1, 2003 |
| Published print: | Sep 1, 2004 |
Identifiers:
| Web of science: | WOS:000224763000005 |
| Scopus: | 2-s2.0-7944226062 |
| Elibrary: | 13464886 |