Реферат: The spontaneous polymerization of a diacetylene monomer was realized out in the clathrate matrix of deoxycholic acid. Clathrate phase --> nonclathrate phase --> clathrate phase transitions were observed in the course of polymerization. The inclusion compound of deoxycholic acid and poly(diacetylene), as well as polymers synthesized in bulk and in the channels of the "host" component, were studied by X-ray analysis, DTA, and Raman spectroscopy. The Raman spectrum of the bulk poly(diacetylene) displayed bands at H 88 and 1536 cm(-1) characteristic of amorphous diacetylene polymers. For the channel poly(diacetylene), seven of ten bands assigned to the crystalline poly(diacetylene) were detected in the 500-2200 cm(-1) range (736, 902, 1177,1283,1515,1582 and 2140 cm(-1)). The X-ray patterns of the polymer produced in the matrix showed a identity period of similar to4.9 Angstrom, while for the bulk polymer, this parameter proved to be 3.8 Angstrom.

Библиографическая ссылка: Chekhova G.N. , Krieger J.H. , Amosov Y.I. , Shubin Y.V. , Basova T.V. , Semenov A.R. , Yudanova L.I.
Spontaneous Polymerization of Diacetylene in Channels of Deoxycholic Acid Clathrate
Polymer Science Series A. 2002. V.44. N6. P.543-550. WOS Scopus РИНЦ

Оригинальная: Чехова Г.Н. , Кригер Ю.Г. , Амосов Ю.И. , Шубин Ю.В. , Басова Т.В. , Семенов А.Р. , Юданова Л.И.
Самопроизвольная полимеризация диацетилена в каналах дезоксихолевой кислоты
Высокомолекулярные соединения. Серия А. 2002. Т.44. №6. С.901-909. РИНЦ CAPlusCA

Даты:

Поступила в редакцию:	6 мар. 2001 г.
Опубликована в печати:	1 июн. 2002 г.

Идентификаторы БД:

Web of science:	WOS:000176645600001
Scopus:	2-s2.0-0036624631
РИНЦ:	13395853

Цитирование в БД:

БД	Цитирований
Web of science	1
Scopus	1