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CO Oxidation over the Pt-Rh System. 3. Reaction on a Heterophase Surface Full article

Journal Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837
Output data Year: 2003, Volume: 78, Number: 1, Pages: 121-127 Pages count : 7 DOI: 10.1023/A:1022522118315
Tags CO oxidation reaction, Heterophase surface, Platinum, Rhodium
Authors Kalinkin A.V. 1 , Pashis A.V. 1 , Bukhtiyarov V.I. 1
Affiliations
1 Boreskov Institute of Catalysis, Novosibirsk 630090, Russia

Funding (3)

1 Russian Foundation for Basic Research 99-03-32444
2 Russian Science Support Foundation
3 International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union 99-01882

Abstract: The reaction of the CO oxidation over a Pt-Rh heterophase surface, which represents 10-20 nm platinum particles located on a rhodium film, which in turn is deposited on an inert support, has been investigated at low pressures (P < 2'10-5 mbar). The results are compared with the data for the clean surfaces of Pt and Rh. In the high-temperature range, the rate of CO2 formation on the heterophase surface is found to be higher than the sum of the rates on individual metals corrected by the surface area of the different metals. The nature of the synergistic effect in the CO oxidation is discussed.
Cite: Kalinkin A.V. , Pashis A.V. , Bukhtiyarov V.I.
CO Oxidation over the Pt-Rh System. 3. Reaction on a Heterophase Surface
Reaction Kinetics and Catalysis Letters. 2003. V.78. N1. P.121-127. DOI: 10.1023/A:1022522118315 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Aug 2, 2002
Accepted: Aug 21, 2002
Published print: Jan 1, 2003
Identifiers:
Web of science: WOS:000181589400016
Scopus: 2-s2.0-0037218563
Elibrary: 13438108
Chemical Abstracts: 2003:151844
Chemical Abstracts (print): 138:276903
OpenAlex: W186694285
Citing:
DB Citing
Web of science 5
Scopus 7
Elibrary 7
OpenAlex 6
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