Performance of Ni/CeO2 Catalysts for Selective CO Methanation in Hydrogen-Rich Gas | Sciact - CRIS-system of Boreskov Institute of Catalysis

Performance of Ni/CeO2 Catalysts for Selective CO Methanation in Hydrogen-Rich Gas Full article

Conference

XX International Conference on Chemical Reactors
03-07 Dec 2012 , Luxemburg

Journal

Chemical Engineering Journal
ISSN: 1385-8947 , E-ISSN: 1873-3212

Output data

Year: 2014, Volume: 238, Pages: 189-197 Pages count : 9 DOI: 10.1016/j.cej.2013.07.034

Tags

Carbon monoxide removal, Effect of chlorine, Hydrogen-rich stream, Ni/CeO2 catalysts, Preferential methanation

Authors

Zyryanova M.M. ^1,2,3 , Snytnikov P.V. ^1,2,3 , Gulyaev R.V. ^1,2 , Amosov Yu.I. ^1,2,3 , Boronin A.I. ^1,2 , Sobyanin V.A. ^1,2,3

Affiliations

1	Boreskov Institute of Catalysis, Pr. Akademika Lavrentieva, 5, Novosibirsk, 630090, Russia
2	Novosibirsk State University, Pirogova St., 2, Novosibirsk, 630090, Russia
3	‘‘UNICAT’’ Ltd., Pr. Akademika Lavrentieva, 5, Novosibirsk, 630090, Russia

Selective CO methanation in H2-rich gas mixture containing 10 vol.% H2O and 20 vol.% CO2 was investigated over chlorine doped 1.8–46.1 wt.% Ni/CeO2 catalysts. BET, XRD, TEM, EDX microchemical analysis and XPS techniques were used for catalyst characterization. Among the catalysts studied, the 9.1 wt.% Ni/CeO2 catalyst with the surface Cl/Ce atomic ratio of 0.15 was the most effective. This catalyst provided the reducing of the CO concentration in H2-rich gas to less than 10 ppm over a wide temperature interval (250–320 °C) keeping the selectivity high (>50%). It was shown that ceria-supported small (20–80 Å) nickel-containing particles provided good activity, while stable chlorine species maintained high selectivity of the catalyst.

Zyryanova M.M. , Snytnikov P.V. , Gulyaev R.V. , Amosov Y.I. , Boronin A.I. , Sobyanin V.A.
Performance of Ni/CeO2 Catalysts for Selective CO Methanation in Hydrogen-Rich Gas
Chemical Engineering Journal. 2014. V.238. P.189-197. DOI: 10.1016/j.cej.2013.07.034 WOS Scopus РИНЦ ANCAN OpenAlex

Published online:	Jul 24, 2013
Published print:	Feb 15, 2014

Web of science:	WOS:000331431500024
Scopus:	2-s2.0-84888835921
Elibrary:	21861356
Chemical Abstracts:	2013:1237270
Chemical Abstracts (print):	160:104162
OpenAlex:	W1990296068

DB	Citing
Web of science	86
Scopus	96
Elibrary	89
OpenAlex	88