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Character of Hydrogen Interaction with Copper Chromite Full article

Journal Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837
Output data Year: 1996, Volume: 58, Number: 1, Pages: 49-56 Pages count : 8 DOI: 10.1007/BF02071104
Tags Catalyst activation, Copper chromite, Hydrogen, Hydrogenation, Sorption kinetics
Authors Simentsova I.I. 1 , Khasin A.V. 1 , Yurieva T.M. 1
Affiliations
1 Federal Scientific Center, Boreskov Institute of Catalysis, Novosibirsk 630090, Russia

Abstract: Hydrogen bonding kinetics have been studied and water amounts produced in H2 interaction with copper chromite CuCr2O4 determined. Two possible interaction mechanisms are suggested: (1) a mechanism involving solid phase oxygen accompanied by water formation; (2) direct redox copper displacement from chromite by hydrogen that requires no oxygen. Initially, when the reaction occurs mainly on the surface, up to 40% of hydrogen is converted according to the first mechanism. Then, the process mainly occurs in the bulk via the second mechanism. Hydrogen sorption by copper chromite proved to be reversible.
Cite: Simentsova I.I. , Khasin A.V. , Yurieva T.M.
Character of Hydrogen Interaction with Copper Chromite
Reaction Kinetics and Catalysis Letters. 1996. V.58. N1. P.49-56. DOI: 10.1007/BF02071104 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Jul 3, 1995
Accepted: Aug 11, 1995
Published print: May 1, 1996
Identifiers:
Web of science: WOS:A1996VH68600008
Scopus: 2-s2.0-0042015686
Elibrary: 13234280
Chemical Abstracts: 1996:636120
Chemical Abstracts (print): 125:286007
OpenAlex: W1964872404
Citing:
DB Citing
Web of science 5
Scopus 6
Elibrary 7
OpenAlex 6
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