Chelate Complex Ni(S2C2H2)2 as a Molecular Model of the Hydrodesulfurization Active Center Научная публикация
| Журнал |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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| Вых. Данные | Год: 1997, Том: 61, Номер: 1, Страницы: 117-122 Страниц : 6 DOI: 10.1007/BF02477522 | ||
| Ключевые слова | Ab initio calculations, Hydrodesulfurization, Ni chelate complex | ||
| Авторы |
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| Организации |
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Реферат:
Electronic states of Ni atom in a square-planar complex Ni(S2C2H2)2 and its molecular adduct with H2S were studied by means ofab initio molecular orbital calculations. H2S adsorption stabilizes the Ni(IV) state (d6) in the complex with the Ni atom shifted from the plane by 0.35 Å.
Библиографическая ссылка:
Yudanov I.V.
, Zakharov I.I.
, Startsev A.N.
, Zhidomirov G.M.
Chelate Complex Ni(S2C2H2)2 as a Molecular Model of the Hydrodesulfurization Active Center
Reaction Kinetics and Catalysis Letters. 1997. V.61. N1. P.117-122. DOI: 10.1007/BF02477522 WOS Scopus РИНЦ CAPlusCA OpenAlex
Chelate Complex Ni(S2C2H2)2 as a Molecular Model of the Hydrodesulfurization Active Center
Reaction Kinetics and Catalysis Letters. 1997. V.61. N1. P.117-122. DOI: 10.1007/BF02477522 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 1 июл. 1996 г. |
| Принята к публикации: | 15 авг. 1996 г. |
| Опубликована в печати: | 1 мая 1997 г. |
Идентификаторы БД:
| Web of science: | WOS:A1997XL65700017 |
| Scopus: | 2-s2.0-0000258330 |
| РИНЦ: | 13265355 |
| Chemical Abstracts: | 1997:545756 |
| Chemical Abstracts (print): | 127:214137 |
| OpenAlex: | W2333488069 |