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Selective Water Sorbents for Multiple Applications, 5. LiBr Confined in Mesopores of Silica Gel: Sorption Properties Научная публикация

Журнал Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837
Вых. Данные Год: 1998, Том: 63, Номер: 1, Страницы: 81-88 Страниц : 8 DOI: 10.1007/BF02475434
Ключевые слова Lithium bromide, Silica gel, Sorption, Vapor
Авторы Gordeeva L.G. 1 , Restuccia G. 2 , Cacciola G. 2 , Aristov Yu.I. 1
Организации
1 Federal Scientific Center, Boreskov Institute of Catalysis, Novosibirsk, Russia
2 lnstitute of Energy Transformation and Accumulation, Messina, Italy

Реферат: This paper presents sorption properties of a selective water sorbent based on mesoporous KSKG silica gel as a host matrix and lithium bromide as a hygroscopic salt. Sorption isobars, isochores and isotherms measured at T=40–120°C and partial vapor pressures of 7.5–81.0 mbar indicated two types of water sorption: 1) formation of a solid crystalline LiBr monohydrate at low amounts of sorbed water, and 2) vapor absorption by the salt solution at higher sorptions. Sorption properties of the LiBr monohydrate are found to change significantly due to salt impregnation into the mesoporous silica gel, whereas the solution confinement to the mesopores did not change its water sorption properties as compared to the bulk solution. Desorption curves follow a first order kinetics in the temperature range of 60–130°C at different vapor pressures.
Библиографическая ссылка: Gordeeva L.G. , Restuccia G. , Cacciola G. , Aristov Y.I.
Selective Water Sorbents for Multiple Applications, 5. LiBr Confined in Mesopores of Silica Gel: Sorption Properties
Reaction Kinetics and Catalysis Letters. 1998. V.63. N1. P.81-88. DOI: 10.1007/BF02475434 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 10 дек. 1996 г.
Принята к публикации: 2 апр. 1997 г.
Опубликована в печати: 1 янв. 1998 г.
Идентификаторы БД:
Web of science: WOS:000072459800013
Scopus: 2-s2.0-0002596377
РИНЦ: 13281472
Chemical Abstracts: 1998:192887
Chemical Abstracts (print): 129:8987
OpenAlex: W2034510111
Цитирование в БД:
БД Цитирований
Web of science 83
Scopus 87
РИНЦ 84
OpenAlex 219
Альметрики: