On the Nature of Factors Determining Reactivity of Strongly Bound Surface Species as Intermediates in Heterogeneous Catalytic Redox Reactions | Sciact - CRIS-system of Boreskov Institute of Catalysis

On the Nature of Factors Determining Reactivity of Strongly Bound Surface Species as Intermediates in Heterogeneous Catalytic Redox Reactions Full article

Journal

Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837

Output data

Year: 1999, Volume: 66, Number: 2, Pages: 337-341 Pages count : 5 DOI: 10.1007/BF02475810

Tags

Klaus reaction, Mechanism of catalytic redox reactions, Methanol synthesis, Selective reduction of nitrogen oxides by hydrocarbons, Strongly bound intermediates

Authors

Sadykov V.A. ¹ , Rozovskii A.Ya. ² , Lunin V.V. ³ , Lin G.I. ² , Alikina G.M. ¹ , Buchtiyarova G.A. ¹ , Zolotovskii B.P. ¹ , Beloshapkin S.A. ⁴

Affiliations

1	Boreskov Institute of Catalysis, Novosibirsk 630090, Russia
2	Topchlev Institute of Petrochemical Synthesis RAS, Moscow, Russia
3	Chemical Department, Lomonosov Moscow State University, Moscow, Russia
4	Department of Natural Sciences, Novisibirsk State University, Novosibirsk, Russia

Funding (2)

1	Russian Foundation for Basic Research	95-03-09622
2	Russian Foundation for Basic Research	95-03-09675

The rate-limiting stage of heterogeneous catalytic redox reactions with participation of strongly bound surface species, such as nitrates, carbonates and sulfites, is the interaction of these heteroatomic oxidants with the reducing agents. It appears to be mainly determined by their bonding strength with the surface, being independent of the nature of the central atom (carbon, sulfur, nitrogen) and the energy of its bond with oxygen.

Sadykov V.A. , Rozovskii A.Y. , Lunin V.V. , Lin G.I. , Alikina G.M. , Buchtiyarova G.A. , Zolotovskii B.P. , Beloshapkin S.A.
On the Nature of Factors Determining Reactivity of Strongly Bound Surface Species as Intermediates in Heterogeneous Catalytic Redox Reactions
Reaction Kinetics and Catalysis Letters. 1999. V.66. N2. P.337-341. DOI: 10.1007/BF02475810 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Jul 13, 1998
Accepted:	Jan 11, 1999
Published print:	Mar 1, 1999

Web of science:	WOS:000079504700021
Scopus:	2-s2.0-0037528746
Elibrary:	13307172
Chemical Abstracts:	1999:613472
Chemical Abstracts (print):	131:205242
OpenAlex:	W1999122596

DB	Citing
Web of science	8
Scopus	4
Elibrary	5
OpenAlex	8