Suppression of Radical-Cationic Benzene Oligomerization on Sulfated Zirconia Full article
| Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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| Output data | Year: 1999, Volume: 67, Number: 1, Pages: 197-203 Pages count : 7 DOI: 10.1007/BF02475848 | ||
| Tags | Benzene, Biphenyl, Cation radicals, ESR, Oligomerization, Sulfated zirconia | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Foundation for Basic Research | 97-03-32566 |
Abstract:
The effect of catalyst activation conditions on transformations of benzene cation radicals on sulfated zirconia has been studied by in situ ESR spectroscopy. After the catalyst activation at 300°C there was no oligomerization of the cation radicals to biphenyl and heavier products, which is observed after catalyst calcination at 500°C. It has been suggested that the oligomerization is suppressed by the presence of strong Brönsted sites on the surface.
Cite:
Bedilo A.F.
, Volodin A.M.
Suppression of Radical-Cationic Benzene Oligomerization on Sulfated Zirconia
Reaction Kinetics and Catalysis Letters. 1999. V.67. N1. P.197-203. DOI: 10.1007/BF02475848 WOS Scopus РИНЦ ANCAN OpenAlex
Suppression of Radical-Cationic Benzene Oligomerization on Sulfated Zirconia
Reaction Kinetics and Catalysis Letters. 1999. V.67. N1. P.197-203. DOI: 10.1007/BF02475848 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Jan 25, 1999 |
| Accepted: | Mar 5, 1999 |
| Published print: | May 1, 1999 |
Identifiers:
| Web of science: | WOS:000080967500030 |
| Scopus: | 2-s2.0-0033137208 |
| Elibrary: | 13315394 |
| Chemical Abstracts: | 1999:613510 |
| Chemical Abstracts (print): | 131:286136 |
| OpenAlex: | W1996527826 |