Acidic Properties of Sulfated Zirconia Научная публикация
| Журнал |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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| Вых. Данные | Год: 2000, Том: 71, Номер: 2, Страницы: 385-391 Страниц : 7 DOI: 10.1023/A:1010304032536 | ||
| Ключевые слова | Acid sites, FTIR, Sulfated zirconia | ||
| Авторы |
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| Организации |
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Реферат:
IR spectroscopy of adsorbed probe molecules (CO, pyridine) is used to characterize the acidic properties of sulfated zirconia derived from zirconium oxide and hydroxide. Their acidic properties are found to be similar. The strength of the Lewis and Brönsted site measured by the frequency shift of adsorbed CO is lower than that in zeolites. It is concluded that sulfated zirconia have no superacid Brönsted and Lewis sites. Brönsted sites capable of protonating pyridine vanish when calcining the catalysts at temperature above 773 K, but the strength and concentration of the Lewis acid sites (LAS) do not change.
Библиографическая ссылка:
Paukshtis E.A.
, Shmachkova V.P.
, Kotsarenko N.S.
Acidic Properties of Sulfated Zirconia
Reaction Kinetics and Catalysis Letters. 2000. V.71. N2. P.385-391. DOI: 10.1023/A:1010304032536 WOS Scopus РИНЦ CAPlusCA OpenAlex
Acidic Properties of Sulfated Zirconia
Reaction Kinetics and Catalysis Letters. 2000. V.71. N2. P.385-391. DOI: 10.1023/A:1010304032536 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Опубликована в печати: | 1 нояб. 2000 г. |
| Поступила в редакцию: | 8 нояб. 2000 г. |
Идентификаторы БД:
| Web of science: | WOS:000167137100026 |
| Scopus: | 2-s2.0-0034319035 |
| РИНЦ: | 13356425 |
| Chemical Abstracts: | 2001:159948 |
| Chemical Abstracts (print): | 134:198655 |
| OpenAlex: | W2158543822 |