Ammoxidation of Methylpyrazine over Phosphorus-Modified Vanadium-Titanium Catalysts Full article
| Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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| Output data | Year: 2003, Volume: 79, Number: 1, Pages: 165-173 Pages count : 9 DOI: 10.1023/A:1024180322453 | ||
| Tags | Methylpyrazine ammoxidation, Phosphorus additives, Vanadium-titanium modified catalysts | ||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Russian Foundation for Basic Research | 01-03-32364 |
| 2 | International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union | 04522 WK |
Abstract:
Vanadium-titanium catalysts modified with phosphorus additives (1-15 wt.% of P2O5) have been studied in methylpyrazine ammoxidation. Introduction of high amounts of the additive (≥ 10 wt.% of P2O5) results in a decrease in activity and selectivity of the catalysts due to formation of low active phase - a ternary compound with the component ratio V : P : Ti ≈ 1 : 1 : 1 with only one type of slightly distorted tetrahedral vanadium (5+) bound via oxygen to phosphorus (5+). The nature of the active sites of the samples modified with 1-5 wt.% of P2O5, similarly to that in the V-Ti-O catalyst, was found to include the V5+ cations strongly bound with TiO2 and located in the significantly distorted octahedral oxygen environment.
Cite:
Bondareva V.M.
, Andrushkevich T.V.
, Lapina O.B.
, Vlasov A.A.
, Dovlitova L.S.
Ammoxidation of Methylpyrazine over Phosphorus-Modified Vanadium-Titanium Catalysts
Reaction Kinetics and Catalysis Letters. 2003. V.79. N1. P.165-173. DOI: 10.1023/A:1024180322453 WOS Scopus РИНЦ ANCAN OpenAlex
Ammoxidation of Methylpyrazine over Phosphorus-Modified Vanadium-Titanium Catalysts
Reaction Kinetics and Catalysis Letters. 2003. V.79. N1. P.165-173. DOI: 10.1023/A:1024180322453 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Jan 28, 2003 |
| Accepted: | Feb 4, 2003 |
| Published print: | May 1, 2003 |
Identifiers:
| Web of science: | WOS:000183538700021 |
| Scopus: | 2-s2.0-0037837392 |
| Elibrary: | 13435137 |
| Chemical Abstracts: | 2003:451653 |
| Chemical Abstracts (print): | 139:214008 |
| OpenAlex: | W71512978 |