In situ Study of Selective Oxidation of Methanol to Formaldehyde over Copper Full article
| Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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| Output data | Year: 2003, Volume: 79, Number: 1, Pages: 181-188 Pages count : 8 DOI: 10.1023/A:1024184423361 | ||||||
| Tags | Copper, Formaldehyde, Methanol oxidation, Photoelectron spectroscopy | ||||||
| Authors |
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| Affiliations |
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Funding (3)
| 1 | Russian Foundation for Basic Research | 00-15-99335 |
| 2 | Russian Foundation for Basic Research | 01-03-32853 |
| 3 | Russian Science Support Foundation |
Abstract:
Selective methanol oxidation to formaldehyde over polycrystalline copper has been studied with the use of in situ XPS combined with mass spectrometry. It has been shown that the copper surface completely covered by methoxy groups exhibits low activity in methanol oxidation, whereas the metallic copper with sub-oxide oxygen is active in the selective oxidation of methanol to formaldehyde. The concentration of the sub-oxide oxygen species seems to correlate with the rate of formaldehyde production.
Cite:
Bukhtiyarov V.I.
, Prosvirin I.P.
, Tikhomirov E.P.
, Kaichev V.V.
, Sorokin A.M.
, Evstigneev V.V.
In situ Study of Selective Oxidation of Methanol to Formaldehyde over Copper
Reaction Kinetics and Catalysis Letters. 2003. V.79. N1. P.181-188. DOI: 10.1023/A:1024184423361 WOS Scopus РИНЦ OpenAlex ANCAN
In situ Study of Selective Oxidation of Methanol to Formaldehyde over Copper
Reaction Kinetics and Catalysis Letters. 2003. V.79. N1. P.181-188. DOI: 10.1023/A:1024184423361 WOS Scopus РИНЦ OpenAlex ANCAN
Dates:
| Submitted: | Jan 28, 2003 |
| Accepted: | Feb 4, 2003 |
| Published print: | May 1, 2003 |
Identifiers:
| ≡ Web of science: | WOS:000183538700023 |
| ≡ Scopus: | 2-s2.0-0038175038 |
| ≡ Elibrary: | 13423731 |
| ≡ OpenAlex: | W60559071 |
| ≡ Chemical Abstracts: | 2003:451655 |
| ≡ Chemical Abstracts (print): | 139:324988 |