Oxidative Addition of Hydrogen in "Reduced" Mo/Al2O3 Catalysts Full article
| Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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| Output data | Year: 2003, Volume: 80, Number: 1, Pages: 97-103 Pages count : 7 DOI: 10.1023/A:1026084226092 | ||
| Tags | Mo/Al2O3 catalysts, Oxidative addition of hydrogen, Temperature-programmed desorption, X-ray photoelectron spectroscopy | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Foundation for Basic Research | 01-03-32417 |
Abstract:
An X-ray photoelectron spectroscopy study of Mo/Al2O3 catalysts prepared via [MoV2O4(C2O4)2(H2O)2]2- complexes showed that after heating the catalysts with hydrogen in the spectrometer chamber, the position of the Mo3d line shifted to higher values of binding energy. This shift is interpreted as oxidative addition of hydrogen to the surface Mo species. A similar phenomenon was observed for a CO treated catalyst. A temperature-programmed desorption study has shown that hydrogen is strongly bounded to Mo and can only be removed from the catalysts at temperatures as high as 500°C.
Cite:
Startsev A.N.
, Klimov O.V.
, Sidyakin M.V.
, Voroshina O.V.
, Tchashkova N.A.
, Zakharov I.I.
, Pashis A.V.
, Kalinkin A.V.
Oxidative Addition of Hydrogen in "Reduced" Mo/Al2O3 Catalysts
Reaction Kinetics and Catalysis Letters. 2003. V.80. N1. P.97-103. DOI: 10.1023/A:1026084226092 WOS Scopus РИНЦ ANCAN OpenAlex
Oxidative Addition of Hydrogen in "Reduced" Mo/Al2O3 Catalysts
Reaction Kinetics and Catalysis Letters. 2003. V.80. N1. P.97-103. DOI: 10.1023/A:1026084226092 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | May 21, 2003 |
| Accepted: | May 27, 2003 |
| Published print: | Sep 1, 2003 |
Identifiers:
| Web of science: | WOS:000185987600014 |
| Scopus: | 2-s2.0-0141973405 |
| Elibrary: | 13443262 |
| Chemical Abstracts: | 2003:787833 |
| Chemical Abstracts (print): | 140:9199 |
| OpenAlex: | W3164417090 |
Citing:
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