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Preparation and Reactivity of Metal-Containing Monomers 53. Synthesis and Stability of a Cluster Monomer (μ-H)Os3(μ-OCNMe2)(CO)9PPh2CH2CH=CH2 in Solution Научная публикация

Журнал Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171
Вых. Данные Год: 2000, Том: 49, Номер: 8, Страницы: 1448-1453 Страниц : 6 DOI: 10.1007/BF02495095
Ключевые слова 1H and 31P NMR spectroscopy, Allyldiphenylphosphine, Carbamoyl ligand, Carbonyl(phosphine)osmium, Cluster monomers, Isomerization, Osmium clusters
Авторы Ershova V.A. 1 , Golovin A.V. 1 , Sheludyakova L.A. 1 , Semyannikov P.P. 1 , Pomogailo S.I. 2 , Pomogailo A.D. 2
Организации
1 Institute of lnorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentieva, 630090 Novosibirsk, Russian Federation
2 Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russian Federation.

Реферат: The stability of the complex (μ-H)Os3(μ-OCNMe2)(CO)9PPh2CH2CH=CH2 (1), which contains a free unsaturated functional group in the terminal ligand PPh2CH2CH=CH2, with respect to isomerization, chelation of the ligand, and other transformations in solutions was examined. No transformations of complex 1 were observed in the course of synthesis from (μ-H)Os3(μ-OCNMe2)(CO)9NMe3 or upon heating in solution. Complex 1 as well as complexes (μ-H)Os3(μ-OCNMe2)(CO)9PHPh2 and (μ-H)Os3(μ-OCNMe2)(CO)9PPh3, which were formed as admixtures, were isolated in the solid state and identified by 1H,1H-{31P}, and1H-{1H} NMR, IR, and Raman spectroscopy and mass spectrometry.
Библиографическая ссылка: Ershova V.A. , Golovin A.V. , Sheludyakova L.A. , Semyannikov P.P. , Pomogailo S.I. , Pomogailo A.D.
Preparation and Reactivity of Metal-Containing Monomers 53. Synthesis and Stability of a Cluster Monomer (μ-H)Os3(μ-OCNMe2)(CO)9PPh2CH2CH=CH2 in Solution
Russian Chemical Bulletin. 2000. V.49. N8. P.1448-1453. DOI: 10.1007/BF02495095 WOS Scopus РИНЦ CAPlusCA OpenAlex
Оригинальная: Ершова В.А. , Головин А.В. , Шелудякова Л.А. , Семянников П.П. , Помогайло С.И. , Помогайло А.Д.
Получение и реакционная способность металлосодержащих мономеров. Сообщение 53. Синтез и устойчивость в растворе кластерного мономера (μ-H)Os3(μ-OCNMe2)(CO)9PPh2CH2CH=CH2
Известия Академии наук. Серия химическая. 2000. №8. С.1455-1460.
Даты:
Поступила в редакцию: 15 дек. 1999 г.
Опубликована в печати: 1 авг. 2000 г.
Идентификаторы БД:
Web of science: WOS:000089808100025
Scopus: 2-s2.0-0034363861
РИНЦ: 13349321
Chemical Abstracts: 2000:753169
Chemical Abstracts (print): 134:56784
OpenAlex: W1992851702
Цитирование в БД:
БД Цитирований
Web of science 5
Scopus 4
OpenAlex 4
Альметрики: